Acid/Base-Free Acyclic Anionic Oxoborane and Iminoborane Bearing Diboryl Groups

M Bao, Y Dai, C Liu, Y Su - Inorganic Chemistry, 2022 - ACS Publications
Anionic oxoboranes and neutral iminoboranes, which are isoelectronic to ketones and
alkynes, respectively, have attracted much attention because of their unique structures and …

New Approaches to N-Heterocyclic-Carbene-Coordinated Iminoborane and Borenium Species

P Cui, R Guo, L Kong, C Cui - Inorganic Chemistry, 2020 - ACS Publications
The synthesis, characterization, and reactivity of an iminoborane–N-heterocyclic carbene
(NHC) adduct were described. The reaction of DmpNHB (OEt) Br [1; Dmp= 2, 6-bis (2, 4, 6 …

Strain induced reactivity of cyclic iminoboranes: the (2+ 2) cycloaddition of a 1 H-1, 3, 2-diazaborepine with ethene

D Gupta, R Einholz, HF Bettinger - Chemical Science, 2024 - pubs.rsc.org
Iminoboranes have gathered immense attention due to their reactivity and potential
applications as isoelectronic and isosteric alkynes. While cyclic alkynes are well …

B N Bond Cleavage and BN Ring Expansion at the Surface of Boron Nitride Nanotubes by Iminoborane

R Sundaram, S Scheiner, AK Roy… - The Journal of Physical …, 2015 - ACS Publications
A new feature of reactivity of iminoborane (HBNH) at the surface of boron nitride nanotube
has been revealed by this theoretical study. The HBNH molecule not only selectively breaks …

[2+ 2] Cycloaddition and Bond Cleavage of Boron Nitride Cages with Iminoborane: A DFT Study

M Anafcheh, S Ghazi Mir Saeed, M Zahedi - Journal of Cluster Science, 2022 - Springer
We have studied the addition of reaction between iminoborane HBNH with the B n N n
cages (n= 12, 16, 28 and 36) for the chemoselectivity (BN bond cleavage and expansion …

The Chemistry of Multibonded Organoboron Compounds

M Devillard, G Alcaraz - PATAI'S Chemistry of Functional …, 2009 - Wiley Online Library
Multiply bonded boron species are fascinating objects of study addressing concerns about
the chemical bonding. Although mostly exemplified with light p‐block elements, the use of …