Understanding specific ion effects and the Hofmeister series
Specific ion effects (SIE), encompassing the Hofmeister Series, have been known for more
than 130 years since Hofmeister and Lewith's foundational work. SIEs are ubiquitous and …
than 130 years since Hofmeister and Lewith's foundational work. SIEs are ubiquitous and …
Ion–ion selectivity of synthetic membranes with confined nanostructures
Synthetic membranes featuring confined nanostructures have emerged as a prominent
category of leading materials that can selectively separate target ions from complex water …
category of leading materials that can selectively separate target ions from complex water …
Tailoring water structure with high-tetrahedral-entropy for antifreezing electrolytes and energy storage at− 80° C
One of unsolved puzzles about water lies in how ion-water interplay affects its freezing point.
Here, we report the direct link between tetrahedral entropy and the freezing behavior of …
Here, we report the direct link between tetrahedral entropy and the freezing behavior of …
How cations affect the electric double layer and the rates and selectivity of electrocatalytic processes
Electrocatalysis is central to the production of renewable fuels and high-value commodity
chemicals. The electrolyte and the electrode together determine the catalytic properties of …
chemicals. The electrolyte and the electrode together determine the catalytic properties of …
Antifreezing hydrogel with high zinc reversibility for flexible and durable aqueous batteries by cooperative hydrated cations
Hydrogels are widely used in flexible aqueous batteries due to their liquid‐like ion
transportation abilities and solid‐like mechanical properties. Their potential applications in …
transportation abilities and solid‐like mechanical properties. Their potential applications in …
Cooperativity in noncovalent interactions
After conquering the atomic structure about a century ago, chemists have been largely
interested in understanding the concept of chemical bond and the formation of a molecule …
interested in understanding the concept of chemical bond and the formation of a molecule …
Surface stratification determines the interfacial water structure of simple electrolyte solutions
The distribution of ions at the air/water interface plays a decisive role in many natural
processes. Several studies have reported that larger ions tend to be surface-active, implying …
processes. Several studies have reported that larger ions tend to be surface-active, implying …
Electrically controlled water permeation through graphene oxide membranes
Controlled transport of water molecules through membranes and capillaries is important in
areas as diverse as water purification and healthcare technologies,,,,,–. Previous attempts to …
areas as diverse as water purification and healthcare technologies,,,,,–. Previous attempts to …
Designing biomimic two-dimensional ionic transport channels for efficient ion sieving
Ion transport is crucial for biological systems and membrane-based technologies from both
fundamental and practical aspects. Unlike biological ion channels, realizing efficient ion …
fundamental and practical aspects. Unlike biological ion channels, realizing efficient ion …
Mechanism of cations suppressing proton diffusion kinetics for electrocatalysis
Proton transfer is crucial for electrocatalysis. Accumulating cations at electrochemical
interfaces can alter the proton transfer rate and then tune electrocatalytic performance …
interfaces can alter the proton transfer rate and then tune electrocatalytic performance …