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Energy transfer photocatalysis: exciting modes of reactivity
Excited (triplet) states offer a myriad of attractive synthetic pathways, including
cycloadditions, selective homolytic bond cleavages and strain-release chemistry …
cycloadditions, selective homolytic bond cleavages and strain-release chemistry …
γ-Amino alcohols via energy transfer enabled brook rearrangement
In the long-standing quest to synthesize fundamental building blocks with key functional
group motifs, photochemistry in the recent past has comprehensively established its …
group motifs, photochemistry in the recent past has comprehensively established its …
Imidazophenothiazine-Based Thermally Activated Delayed Fluorescence Materials with Ultra-Long-Lived Excited States for Energy Transfer Photocatalysis
Triplet-triplet energy transfer (EnT) is a powerful activation pathway in photocatalysis that
unlocks new organic transformations and improves the sustainability of organic synthesis …
unlocks new organic transformations and improves the sustainability of organic synthesis …
Three-component photochemical 1, 2, 5-trifunctionalizations of alkenes toward densely functionalized lynchpins
Radical remote 1, n-difunctionalization reactions (n> 2) of alkenes are powerful tools to
efficiently introduce functional groups with selected distances into target molecules. Among …
efficiently introduce functional groups with selected distances into target molecules. Among …
Photocatalytic 1, 2-iminosulfonylation and remote 1, 6-iminosulfonylation of olefins
XL Luo, SS Li, YS Jiang, F Liu, SH Li, PJ **a - Organic Letters, 2023 - ACS Publications
A new class of iminosulfonylation reagents were developed and extensively used in the 1, 2-
iminosulfonylation of various olefins. Olefins containing bioactive molecules, such as …
iminosulfonylation of various olefins. Olefins containing bioactive molecules, such as …
Strain-enabled radical spirocyclization cascades: rapid access to spirocyclobutyl lactones and–lactams
Spirocyclobutane derivatives have gained significant attention in drug discovery programs
due to their broad spectrum of biological activities and clinical applications. Ring-strain in …
due to their broad spectrum of biological activities and clinical applications. Ring-strain in …
Metal-free photosensitized aminosulfonylation of alkenes: a practical approach to β-amido sulfones
M Chen, W Sun, J Yang, LL Yuan, JQ Chen, J Wu - Green Chemistry, 2023 - pubs.rsc.org
A general and environmentally friendly organic photo-induced strategy was developed for
the synthesis of diverse alkyl-substituted β-amino sulfone derivatives, including primary …
the synthesis of diverse alkyl-substituted β-amino sulfone derivatives, including primary …
Photoinduced Difunctionalization of Diazenes Enabled by N–N Radical Coupling
YS Jiang, SS Li, XL Luo, LN Chen, DN Chen… - Organic …, 2023 - ACS Publications
In this study, a metal-free difunctionalization strategy for diazenes was developed using a
range of bifunctionalization reagents. This strategy involves a unique N (sp3)–N (sp2) …
range of bifunctionalization reagents. This strategy involves a unique N (sp3)–N (sp2) …
Visible-Light-Mediated Two Transient C(sp3) Radical-Selective Cross-Coupling via Nickel Catalyst Continuous Capture: Synthesis of Pyrroline Derivatives
B Yang, XY Wang, XT Huang, ZY Liu, X Li… - ACS …, 2023 - ACS Publications
Two C (sp3) radicals cross-coupling as a straightforward method for constructing C (sp3)–C
(sp3) bonds has attracted extensive attention from chemists. Unfortunately, the strategy is …
(sp3) bonds has attracted extensive attention from chemists. Unfortunately, the strategy is …
Photocatalytic Unsymmetrical Diamination of Styrenes, Indoles, and Benzofurans Facilitated by Benzotriazolyl and Iminyl Radicals
Utilizing energy transfer catalysis, this research employed the bifunctional reagents
benzotriazole carboxylic acid oxime esters to simultaneously generate benzotriazole and …
benzotriazole carboxylic acid oxime esters to simultaneously generate benzotriazole and …