Reactivity of metal–oxo clusters towards biomolecules: from discrete polyoxometalates to metal–organic frameworks
Metal–oxo clusters hold great potential in several fields such as catalysis, materials science,
energy storage, medicine, and biotechnology. These nanoclusters of transition metals with …
energy storage, medicine, and biotechnology. These nanoclusters of transition metals with …
Exploiting interactions between polyoxometalates and proteins for applications in (bio) chemistry and medicine
S Lentink, DE Salazar Marcano… - Angewandte …, 2023 - Wiley Online Library
The specific interactions of anionic metal‐oxo clusters, known as polyoxometalates (POMs),
with proteins can be leveraged for a wide range of analytical and biomedical applications …
with proteins can be leveraged for a wide range of analytical and biomedical applications …
The novel application of polyoxometalates for achieving sludge deep dewatering using low-temperature thermal hydrolysis pretreatment
Traditional thermal hydrolysis pretreatment (THP) for sludge deep dewatering is energy-
intensive and poses the risk of generating bio-toxic substances that affect downstream …
intensive and poses the risk of generating bio-toxic substances that affect downstream …
Speciation atlas of polyoxometalates in aqueous solutions
Speciation is the key parameter in solution chemistry that describes the composition,
concentration, and oxidation state of each chemical form of an element present in a sample …
concentration, and oxidation state of each chemical form of an element present in a sample …
All‐Inorganic Polyoxometalates Act as Superchaotropic Membrane Carriers
Polyoxometalates (POMs) are known antitumoral, antibacterial, antiviral, and anticancer
agents and considered as next‐generation metallodrugs. Herein, a new biological …
agents and considered as next‐generation metallodrugs. Herein, a new biological …
Solution-processed formation of DNA-origami-supported polyoxometalate multi-level switches with countercation-controlled conductance tunability
E Vogelsberg, M Moors, AS Sorokina… - Chemistry of …, 2023 - ACS Publications
We report a chemically programmed design and the switching characteristics of a functional
metal–DNA-origami–polyoxometalate (POM) material obtained from the solution-processed …
metal–DNA-origami–polyoxometalate (POM) material obtained from the solution-processed …
Effect of the Polyanion Structure on the Mechanism of Alcohol Oxidation with H2O2 Catalyzed by Zr-Substituted Polyoxotungstates
Zr-monosubstituted polyoxometalates (Zr-POMs) of the Lindqvist (Bu4N) 6 [{W5O18Zr (μ-
OH)} 2](1), Keggin (Bu4N) 8 [{PW11O39Zr (μ-OH)} 2](2), and Wells–Dawson (Bu4N) 11.3 …
OH)} 2](1), Keggin (Bu4N) 8 [{PW11O39Zr (μ-OH)} 2](2), and Wells–Dawson (Bu4N) 11.3 …
Hybrid functional materials merging polyoxometalates and biomolecules: From synthesis to applications
Recent developments in synthetic strategies have enabled the formation of increasingly
complex hybrid functional materials incorporating both organic and inorganic components …
complex hybrid functional materials incorporating both organic and inorganic components …
Polyoxometalates: metallodrug agents for combating amyloid aggregation
Alzheimer's disease (AD) is a devastating neurodegenerative disease that affects∼ 50
million people globally. The accumulation of amyloid-β (Aβ) plaques, a predominant …
million people globally. The accumulation of amyloid-β (Aβ) plaques, a predominant …
Tuning Reactivity of Zr-Substituted Keggin Phosphotungstate in Alkene Epoxidation through Balancing H2O2 Activation Pathways: Unusual Effect of Base
The Zr-monosubstituted Keggin-type dimeric phosphotungstate (Bu4N) 8 [{PW11O39Zr (μ–
OH)(H2O)} 2](1) efficiently catalyzes epoxidation of C═ C bonds in various kinds of alkenes …
OH)(H2O)} 2](1) efficiently catalyzes epoxidation of C═ C bonds in various kinds of alkenes …