In recent years, there has been growing interest in photo-mediated processes. Herein, this
review aims to give a summary concerning photoinduced processes in which pyrylium salts …

The first Suzuki− Miyaura cross-coupling reactions of the synthetically versatile aryl O-
carbamate and O-sulfamate groups are described. The transformations utilize the …

By employing enaminones and thiuram disulfides as starting materials, the frontiers of
Newman–Kwart rearrangement have been expanded to the alkenyl system for the first time …

DFT calculations have been used to explore the full catalytic cycle of the Suzuki–Miyaura
coupling between PhBr and PhB (OH) 3− with four different palladium monophosphine …

Abstract The Newman Kwart Rearrangement (NKR) offers an efficient and high‐yielding
method for producing substituted thiophenols from phenols. While an industrially important …

Since the emergence of pseudo-C2-symmetric chiral phosphoric acids (CPA), much work
has been done to utilize these systems in stereoselective, organocatalytic processes …

For more than a century, copper has been used as a promoter in cross-coupling reactions of
aryl halides with diverse nucleophiles to construct C–C and C-heteroatom bonds. The …

Density functional theory, coupled‐cluster theory, and transition state theory are used to
build a computational model of the kinetics of phosphine‐free cobalt‐catalyzed …

The Newman–Kwart rearrangement is perhaps the quintessential method for the synthesis
of thiophenols from the corresponding phenol. However, the high thermal conditions …

The success of near-infrared (NIR) fluorescence to be employed for intraoperative imaging
relies on the ability to develop a highly stable, NIR fluorescent, nontoxic, biocompatible, and …