Impact of 3d Metal Ions on the Magnetic Dynamics in Isostructural Tetranuclear Butterfly {Ni2IIDy2III} and {Co2IIDy2III} Complexes
This paper describes the synthesis, structures, and magnetic properties of four isostructural
butterfly-type heterometallic tetranuclear 3d-4f complexes,[Ni2Dy2 (HL1) 2 (μ3–OH) 2 (piv) …
butterfly-type heterometallic tetranuclear 3d-4f complexes,[Ni2Dy2 (HL1) 2 (μ3–OH) 2 (piv) …
A terpyridyl-imidazole based europium tris-(β-diketonate) complex as an efficient molecular luminescent thermometer and single component white light emitter via …
The thermosensing and thermochromic behavior of one of our recently reported terpyridyl-
imidazole based ternary europium tris-(β-diketonate) complexes of the composition [Eu (tta) …
imidazole based ternary europium tris-(β-diketonate) complexes of the composition [Eu (tta) …
Lanthanoid coordination prompts unusually distorted pseudo-octahedral Ni II coordination in heterodinuclear Ni–Ln complexes: synthesis, structure and …
B Dutta, T Guizouarn, F Pointillart, K Kotrle… - Dalton …, 2023 - pubs.rsc.org
In this work, a new family of binuclear NiII–LnIII complexes with the formula [NiLn (L) 2 (NO3)
3]· 0.5 H2O (Ln= Gd, 1; Tb, 2; Dy, 3; Ho, 4; Er, 5; Yb, 6; Y, 7) was synthesized using a …
3]· 0.5 H2O (Ln= Gd, 1; Tb, 2; Dy, 3; Ho, 4; Er, 5; Yb, 6; Y, 7) was synthesized using a …
Understanding electrostatics and covalency effects in highly anisotropic organometallic sandwich dysprosium complexes [Dy (C m R m) 2](where R= H, SiH 3, CH 3 …
In this article, we have thoroughly studied the electronic structure and 4f-ligand covalency of
six mononuclear dysprosium organometallic sandwich complexes [Dy (CmRm) 2] …
six mononuclear dysprosium organometallic sandwich complexes [Dy (CmRm) 2] …
Enhancing magnetic relaxation through subcomponent self-assembly from a Dy 2 to Dy 4 grid
XL Li, Z Ma, J Wu, Q Zhou, J Tang - Dalton Transactions, 2022 - pubs.rsc.org
The subcomponent self-assembly of 4, 6-dihydrazinopyrimidine and o-vanillin/
salicylaldehyde with different DyIII salts leads to the formation of Dy2 (1–3) and grid-like Dy4 …
salicylaldehyde with different DyIII salts leads to the formation of Dy2 (1–3) and grid-like Dy4 …
In situ hydrolysis of a carbophosphazene ligand leads to one-dimensional lanthanide coordination polymers. Synthesis, structure and dynamic magnetic studies
An in situ hydrolysis of the P–Cl bonds of the carbophosphazene [{NC (NMe2)} 2
{NPCl2}](LPCl2) in the presence of hydrated lanthanide (III) nitrates in a dichloromethane …
{NPCl2}](LPCl2) in the presence of hydrated lanthanide (III) nitrates in a dichloromethane …
Tuning Quantum Tunneling in Isomorphic {MII2DyIII2} “Butterfly” System via 3d-4f Magnetic Interaction
GP Li, HZ Tang, RC Gao, YY Wang, X Sun… - Crystal Growth & …, 2023 - ACS Publications
In order to probe the magnetic relaxation mechanism of 3d-4f complexes systematically, two
“Butterfly” MII2DyIII2 complexes related to our previously reported butterfly …
“Butterfly” MII2DyIII2 complexes related to our previously reported butterfly …
Terpyridyl-Imidazole Based Ligand Coordinated to Ln(Hexafluoroacetyl acetonate)3 Core: Synthesis, Structural Characterization, Luminescence Properties, and …
A new array of ternary lanthanide complexes of the form [Ln (hfa) 3 (tpy-HImzphen)] have
been synthesized and thoroughly characterized wherein Ln= LaIII (1), EuIII (2), SmIII (3), and …
been synthesized and thoroughly characterized wherein Ln= LaIII (1), EuIII (2), SmIII (3), and …
Unravelling the electronic structure, bonding, and magnetic properties of inorganic dysprosocene analogues [Dy (E 4) 2]−(E= N, P, As, CH)
I Tarannum, SK Singh - Physical Chemistry Chemical Physics, 2025 - pubs.rsc.org
Organometallic sandwich complexes of Dy (III) ion are ubiquitous for designing high-
temperature single-ion magnets with blocking temperatures close to the liquid nitrogen …
temperature single-ion magnets with blocking temperatures close to the liquid nitrogen …
Structural isomerism-tuned magnetisation relaxation dynamics in lanthanide coordination complexes
The eigenspectrum and eigenvectors of the 2F7/2 ground multiplets of two structural isomer
coordination complexes, Yb (trenovan)(H3trenovan= tris (((3-methoxysalicylidene) amino) …
coordination complexes, Yb (trenovan)(H3trenovan= tris (((3-methoxysalicylidene) amino) …