Microscopic imaging techniques for molecular assemblies: electron, atomic force, and confocal microscopies

R Kubota, W Tanaka, I Hamachi - Chemical Reviews, 2021 - ACS Publications
Self-assembly is promising for construction of a wide variety of supramolecular assemblies,
whose 1D/2D/3D structures are typically relevant to their functions. In-depth understanding …

Supramolecular polymers: Recent advances based on the types of underlying interactions

HQ Peng, W Zhu, WJ Guo, Q Li, S Ma, C Bucher… - Progress in Polymer …, 2023 - Elsevier
Supramolecular polymers are, in broad brushstrokes, self-assembled structures built up from
small building blocks via the use of noncovalent interactions. In favorable cases …

Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization

E Weyandt, L Leanza, R Capelli, GM Pavan… - Nature …, 2022 - nature.com
Multi-component systems often display convoluted behavior, pathway complexity and
coupled equilibria. In recent years, several ways to control complex systems by manipulating …

Chirality-controlled supramolecular donor–acceptor copolymerization with distinct energy transfer efficiency

R Liao, F Wang, Y Guo, Y Han… - Journal of the American …, 2022 - ACS Publications
Chirality delivers substantial value to the field of supramolecular polymers, not only serving
as a probe to monitor the dynamic assembly process but providing access to chiroptical …

Controlled noncovalent synthesis of secondary supramolecular polymers

S Sarkar, R Laishram, D Deb… - Journal of the American …, 2023 - ACS Publications
Dynamic supramolecular polymers, with their functional similarities to classical covalent
polymers and their adaptive and self-repairing nature reminiscent of biological assemblies …

Pathway complexity in supramolecular copolymerization and blocky star copolymers by a hetero-seeding effect

P Khanra, AK Singh, L Roy, A Das - Journal of the American …, 2023 - ACS Publications
This study unravels the intricate kinetic and thermodynamic pathways involved in the
supramolecular copolymerization of the two chiral dipolar naphthalene monoimide (NMI) …

Amplification of molecular asymmetry during the hierarchical self-assembly of foldable azobenzene dyads into nanotoroids and nanotubes

T Saito, T Kajitani, S Yagai - Journal of the American Chemical …, 2022 - ACS Publications
The amplification of molecular asymmetry through self-assembly is a phenomenon that not
only comprehends the origin of homochirality in nature but also produces chiroptically active …

Shape-assisted self-assembly

JF Woods, L Gallego, P Pfister, M Maaloum… - Nature …, 2022 - nature.com
Self-assembly and molecular recognition are critical processes both in life and material
sciences. They usually depend on strong, directional non-covalent interactions to gain …

Self-assembled macrocycles: design strategies and emerging functions

D Talukdar, JM Kumar, B Gole - Crystal Growth & Design, 2023 - ACS Publications
Molecular self-assembly is an essential process in biological systems to perform
sophisticated functions. Along the same line, development of artificial self-assembled …

Spontaneous resolution of racemic cage-catenanes via diastereomeric enrichment at the molecular level and subsequent narcissistic self-sorting at the …

P Li, Z Sun, J Chen, Y Zuo, C Yu, X Liu… - Journal of the …, 2022 - ACS Publications
The spontaneous resolution of racemates, from natural compounds to artificial structures,
has long been pursued to shed light on the origin of homochirality in life. Even though …