Orbital occupancy and spin polarization: from mechanistic study to rational design of transition metal-based electrocatalysts toward energy applications

VH Do, JM Lee - ACS nano, 2022 - ACS Publications
Over the past few decades, development of electrocatalysts for energy applications has
extensively transitioned from trial-and-error methodologies to more rational and directed …

Advancements in Ruthenium (Ru)‐Based Heterostructure Catalysts: Overcoming Bottlenecks in Catalysis for Hydrogen Evolution Reaction

Y Kuang, F Yang, L Feng - Advanced Energy Materials, 2024 - Wiley Online Library
Investigating clean and sustainable hydrogen generation from water splitting requires cost‐
effective and highly efficient electrocatalysts for the hydrogen evolution reaction (HER) …

Perovskites in catalysis and electrocatalysis

J Hwang, RR Rao, L Giordano, Y Katayama, Y Yu… - Science, 2017 - science.org
Catalysts for chemical and electrochemical reactions underpin many aspects of modern
technology and industry, from energy storage and conversion to toxic emissions abatement …

Recent progress in voltage control of magnetism: Materials, mechanisms, and performance

C Song, B Cui, F Li, X Zhou, F Pan - Progress in Materials Science, 2017 - Elsevier
Voltage control of magnetism (VCM) is attracting increasing interest and exciting significant
research activity driven by its profound physics and enormous potential for application. This …

Physics of ultrathin films and heterostructures of rare-earth nickelates

S Middey, J Chakhalian, P Mahadevan… - Annual Review of …, 2016 - annualreviews.org
The electronic structure of transition metal oxides featuring correlated electrons can be
rationalized within the Zaanen-Sawatzky-Allen framework. Following a brief description of …

Colloquium: Emergent properties in plane view: Strong correlations at oxide interfaces

J Chakhalian, JW Freeland, AJ Millis… - Reviews of Modern …, 2014 - APS
Finding new collective electronic states in materials is one of the fundamental goals of
condensed matter physics. Atomic-scale superlattices formed from transition metal oxides …

Surface symmetry-breaking and strain effects on orbital occupancy in transition metal perovskite epitaxial films

D Pesquera, G Herranz, A Barla, E Pellegrin… - Nature …, 2012 - nature.com
The electron occupancy of 3d-orbitals determines the properties of transition metal oxides.
This can be achieved, for example, through thin-film heterostructure engineering of AB O3 …

Critical thickness and orbital ordering in ultrathin films

M Huijben, LW Martin, YH Chu, MB Holcomb, P Yu… - Physical Review B …, 2008 - APS
Detailed analysis of transport, magnetism, and x-ray absorption spectroscopy
measurements on ultrathin La 0.7 Sr 0.3 MnO 3 films with thicknesses from 3 to 70 unit cells …

The role of strain in oxygen evolution reaction

Z Feng, C Dai, Z Zhang, X Lei, W Mu, R Guo… - Journal of Energy …, 2024 - Elsevier
The oxygen evolution reaction (OER) is a crucial step in metal-air batteries and water
splitting technologies, playing a significant role in the efficiency and achievable heights of …

Orbital reflectometry of oxide heterostructures

E Benckiser, MW Haverkort, S Brück, E Goering… - Nature Materials, 2011 - nature.com
The occupation of d orbitals controls the magnitude and anisotropy of the inter-atomic
electron transfer in transition-metal oxides and hence exerts a key influence on their …