Catalytic oxidation of alcohols: Recent advances

MN Kopylovich, APC Ribeiro, ECBA Alegria… - Advances in …, 2015 - Elsevier
This review concerns metal-catalyzed reactions of oxidation of alcohols to the respective
products, mainly ketones and aldehydes, mostly within the period of 2010–2014. Both …

Metal‐Terpyridine Complexes in Catalytic Application–A Spotlight on the Last Decade

A Winter, US Schubert - ChemCatChem, 2020 - Wiley Online Library
Abstract 2, 2′: 6′, 2′′‐Terpyridine (tpy) and its derivatives represent highly versatile
ligands for the complexation of transition metal ions. Today, such complexes are employed …

Intramolecular proton transfer boosts water oxidation catalyzed by a Ru complex

R Matheu, MZ Ertem, J Benet-Buchholz… - Journal of the …, 2015 - ACS Publications
We introduce a new family of complexes with the general formula [Ru n (tda)(py) 2] m+(n= 2,
m= 0, 1; n= 3, m= 1, 2+; n= 4, m= 2, 3 2+), with tda2–being [2, 2′: 6′, 2 ″-terpyridine]-6, 6 …

Enhancing Photoredox Catalysis in Aqueous Environments: Ruthenium Aqua Complex Derivatization of Graphene Oxide and Graphite Rods for Efficient Visible-Light …

S Affès, AM Stamatelou, X Fontrodona… - … applied materials & …, 2023 - ACS Publications
A ruthenium aqua photoredox catalyst has been successfully heterogeneneized on
graphene oxide (GO@ trans-fac-3) and graphite rods (GR@ trans-fac-3) for the first time and …

Comparison of rhenium–porphyrin dyads for CO 2 photoreduction: photocatalytic studies and charge separation dynamics studied by time-resolved IR spectroscopy

CD Windle, MW George, RN Perutz, PA Summers… - Chemical …, 2015 - pubs.rsc.org
We report a study of the photocatalytic reduction of CO2 to CO by zinc porphyrins covalently
linked to [ReI (2, 2′-bipyridine)(CO) 3L]+/0 moieties with visible light of wavelength> 520 …

Diazines and Triazines as Building Blocks in Ligands for Metal-Mediated Catalytic Transformations

JS Doll, FJ Becker, DA Roşca - ACS Organic & Inorganic Au, 2023 - ACS Publications
Pyridine is a ubiquitous building block for the design of very diverse ligand platforms, many
of which have become indispensable for catalytic transformations. Nevertheless, the …

Metallacarboranes as photoredox catalysts in water

I Guerrero, Z Kelemen, C Viñas… - … A European Journal, 2020 - Wiley Online Library
Metallacarboranes with the shape of the Greek letter θ, such as [Co (C2B9H11) 2]−, were
tested, for the first time, as efficient photoredox catalysts in the oxidation of aromatic and …

Visible light driven benzyl alcohol dehydrogenation in a dye-sensitized photoelectrosynthesis cell

W Song, AK Vannucci, BH Farnum… - Journal of the …, 2014 - ACS Publications
Light-driven dehydrogenation of benzyl alcohol (BnOH) to benzaldehyde and hydrogen has
been shown to occur in a dye-sensitized photoelectrosynthesis cell (DSPEC). In the DSPEC …

Molecular and supported ruthenium complexes as photoredox oxidation catalysts in water

E Clerich, S Affès, E Anticó, X Fontrodona… - Inorganic Chemistry …, 2022 - pubs.rsc.org
A new bidentate pyridylpyrazole ligand functionalized with the pyrene group, 3-(2-pyridyl)-1-
(pyrazolyl) methylpyrene (pypz–pyr), was synthesized, together with a successful …

A stand-alone cobalt bis (dicarbollide) photoredox catalyst epoxidates alkenes in water at extremely low catalyst load

I Guerrero, C Viñas, I Romero, F Teixidor - Green Chemistry, 2021 - pubs.rsc.org
The cobalt bis (dicarbollide) complex, Na [3, 3′-Co (η5-1, 2-C2B9H11)(Na [1]), is an
effective photoredox catalyst for the oxidation of alkenes to epoxides in water. Advantageous …