The catalytic cycles for the H2-hydrogenation (H) and transfer hydrogenation (T) of C O
and C N bonds catalyzed by over 100 ruthenium hydride complexes in organic and …

Formation of stable iron hydrides on more nucleophilic (electron-rich) metal centers than
those found in hydrogenases with CO ligands would inhibit or at least slow down function …

Although reversible covalent activation of molecular hydrogen (H2) is a common reaction at
transition metal centers, it has proven elusive in compounds of the lighter elements. We …

The use of carbon dioxide as a raw material for chemical syntheses is an ecologically and
economically valuable extension to the carbon sources used at the present time. In order to …

Facile Heterolytic Cleavage of Dihydrogen by Phosphines and Boranes | Journal of the
American Chemical Society Recently Viewedclose modal ACS ACS Publications C&EN CAS …

Transition metal hydride complexes are usually amphoteric, not only acting as hydride
donors, but also as Brønsted–Lowry acids. A simple additive ligand acidity constant …

Dihydrogen complexation with retention of the H–H bond, once an exotic concept, has by
now appeared in a very wide range of contexts. Three structural types are currently …

The ternary system consisting of [RuCl2 (η6-benzene)] 2, N-tosylethylenediamine or
ethanolamine, and KOH (Ru: amine: KOH= 1: 1: 2 molar ratio) catalyzes reversible hydrogen …

There is a marvelous analogy between the metal–olefin π bonding model first brought to
light by Dewar 50 years ago and that of σ-bond coordination discovered by us 17 years ago …

A comprehensive overview on homogeneous catalytic hydrogenation of carboxylic acids
and its derivatives as well as carbonic acid derivatives with transition metal-based molecular …