Metallacrowns: supramolecular constructs with potential in extended solids, solution-state dynamics, molecular magnetism, and imaging

JC Lutter, CM Zaleski, VL Pecoraro - Advances in Inorganic Chemistry, 2018 - Elsevier
Metallacrown (MC) research grows each year, in particular with regard to applications of
these molecules. This review will focus on the properties and applications of these …

Visible, near-infrared, and dual-range luminescence spanning the 4f series sensitized by a gallium (III)/lanthanide (III) metallacrown structure

EV Salerno, SV Eliseeva, BL Schneider… - The Journal of …, 2020 - ACS Publications
Lanthanide (III) ions (Ln3+) in coordination compounds exhibit unique luminescence
properties with narrow and characteristic ff transitions throughout the visible and near …

Iodinated Metallacrowns: Toward Combined Bimodal Near‐Infrared and X‐Ray Contrast Imaging Agents

JC Lutter, SV Eliseeva, G Collet… - … A European Journal, 2020 - Wiley Online Library
Multimodal probes capable of combining imaging modalities within a single molecule are in
high demand today as they can provide information at both molecular and anatomical levels …

In vitro and in silico study of the biological activity of manganese (III) inverse-[9-MC-3]-metallacrowns and manganese (II) complexes with the anti-inflammatory drugs …

GD Geromichalos, A Tarushi, K Lafazanis… - Journal of inorganic …, 2018 - Elsevier
In the present contribution, the biological properties of four manganese complexes with the
non-steroidal anti-inflammatory drugs sodium diclofenac (Nadicl) or indomethacin (Hindo) in …

pH‐Responsive Switching Properties of a Water‐Soluble Metallamacrocyclic Phenylalaninehydroximate La (III)–Cu (II) Complex: Insight into Tuning Protonation …

MA Katkova, GS Zabrodina… - European Journal of …, 2019 - Wiley Online Library
The water‐soluble copper (II)‐lanthanum (III) complex based on phenylalaninehydroximate
ligands La (H2O) 4 [15‐MCCuPhalaha‐5](Cl) 3 (1) has been synthesized and characterized …

A step-ladder manganese (iii) metallacrown hosting mefenamic acid and a manganese (ii)–mefanamato complex: synthesis, characterization and cytotoxic activity

A Tarushi, GD Geromichalos, K Lafazanis… - New Journal of …, 2018 - pubs.rsc.org
The interaction of Mn (II) with the non-steroidal anti-inflammatory drug mefenamic acid
(Hmef) in the presence or absence of salicylaldoxime (H2sao) leads to the formation of the …

Peculiarities of crystal structures and photophysical properties of Ga III/Ln III metallacrowns with a non-planar [12-MC-4] core

TN Nguyen, SV Eliseeva, CY Chow… - Inorganic Chemistry …, 2020 - pubs.rsc.org
A new series of gallium (III)/lanthanide (III) metallacrown (MC) complexes (Ln-1) was
synthesized by the direct reaction of salicylhydroxamic acid (H3shi) with GaIII and LnIII …

Lanthanide Identity Governs Guest‐Induced Dimerization in LnIII[15‐MC N(L‐pheHA)‐5])3+ Metallacrowns

C Sgarlata, BL Schneider, V Zito… - … A European Journal, 2021 - Wiley Online Library
Abstract Series of lanthanide‐containing metallic coordination complexes are frequently
presented as structurally analogous, due to the similar chemical and coordinative properties …

Host–Guest Chemistry of Metallacrowns

BL Schneider, VL Pecoraro - Advances in Metallacrown Chemistry, 2022 - Springer
Host–guest chemistry emerged as a field in the late 1960s beginning in the context of
organic hosts with simple alkali metallic guests and soon expanding to more complex …

Magnetic Properties of LnIII–CuII 15‐Metallacrown‐5 Dimers with Terephthalate (LnIII = Pr, Nd, Sm, Eu)

AV Pavlishchuk, SV Kolotilov, M Zeller… - European Journal of …, 2018 - Wiley Online Library
Metathesis of the isomorphous 15‐metallacrown‐5 complexes {[LnCu5 (GlyHA) 5
(SO4)(H2O) 6.5]} 2 (SO4)· 6H2O (LnIII= Pr, Nd, Sm, Eu; GlyHA2–= glycinehydroxamate) with …