Clusters of actinides with oxide, peroxide, or hydroxide bridges
Metal oxide clusters, especially transition-metal polyoxometalates, have been studied for
decades because they provide a rare opportunity to study nanoscale materials with well …
decades because they provide a rare opportunity to study nanoscale materials with well …
A comprehensive comparison of transition-metal and actinyl polyoxometalates
While the d0 transition-metal POMs of Group V (V5+, Nb5+, Ta5+) and Group VI (Mo6+,
W6+) have been known for more than a century, the actinyl peroxide POMs, specifically …
W6+) have been known for more than a century, the actinyl peroxide POMs, specifically …
Captivation with encapsulation: a dozen years of exploring uranyl peroxide capsules
Uranyl peroxide clusters containing from 16 to 124 uranyl ions self-assemble in aqueous
solution and exhibit tremendous topological complexity. Most of these clusters are cages …
solution and exhibit tremendous topological complexity. Most of these clusters are cages …
Diphosphates and diphosphonates in polyoxometalate chemistry
In the wide area of polyoxometalate (POM) chemistry, diphosphate/diphosphonate-based
POMs represent a more recent area of study. However, in this short time it has emerged to …
POMs represent a more recent area of study. However, in this short time it has emerged to …
The Key Role of U28 in the Aqueous Self‐Assembly of Uranyl Peroxide Nanocages
For 11 years now, the structural diversity and aesthetic beauty of uranyl–peroxide capsules
have fascinated researchers from the diverse fields of mineralogy, polyoxometalate …
have fascinated researchers from the diverse fields of mineralogy, polyoxometalate …
Uranyl peroxide oxalate cage and core–shell clusters containing 50 and 120 uranyl ions
Cage clusters built from uranyl hexagonal bipyramids and oxalate ligands crystallize from
slightly acidic aqueous solution under ambient conditions, facilitating structure analysis …
slightly acidic aqueous solution under ambient conditions, facilitating structure analysis …
Stability of solid uranyl peroxides under irradiation
The effects of radiation on a variety of uranyl peroxide compounds were examined using γ-
rays and 5 MeV He ions, the latter to simulate α-particles. The studied materials were …
rays and 5 MeV He ions, the latter to simulate α-particles. The studied materials were …
Syntheses, structures, luminescence, and photocatalytic properties of a series of uranyl coordination polymers
W Yang, WG Tian, XX Liu, L Wang… - Crystal growth & …, 2014 - ACS Publications
A new series of uranium coordination polymers have been hydrothermally synthesized by
using 4, 4′-oxidiphthalic acid (H4L) in the presence of N-bearing species, namely,(H2dpa) …
using 4, 4′-oxidiphthalic acid (H4L) in the presence of N-bearing species, namely,(H2dpa) …
Metal-controlled assembly of uranyl diphosphonates toward the design of functional uranyl nanotubules
Two uranyl nanotubules with elliptical cross sections were synthesized in high yield from
complex and large oxoanions using hydrothermal reactions of uranyl salts with 1, 4 …
complex and large oxoanions using hydrothermal reactions of uranyl salts with 1, 4 …
Time-resolved self-assembly of a fullerene-topology core–shell cluster containing 68 uranyl polyhedra
A complex core–shell cluster consisting of 68 uranyl peroxo polyhedra, 16 nitrate groups,
and∼ 44 K+ and Na+ cations was obtained by self-assembly in alkaline aqueous solution …
and∼ 44 K+ and Na+ cations was obtained by self-assembly in alkaline aqueous solution …