Software update: The ORCA program system—Version 5.0

F Neese - Wiley Interdisciplinary Reviews: Computational …, 2022 - Wiley Online Library
Abstract Version 5.0 of the ORCA quantum chemistry program suite was released in July
2021. ORCA 5.0 represents a major improvement over all previous versions of ORCA and …

Best‐practice DFT protocols for basic molecular computational chemistry

M Bursch, JM Mewes, A Hansen… - Angewandte Chemie …, 2022 - Wiley Online Library
Nowadays, many chemical investigations are supported by routine calculations of molecular
structures, reaction energies, barrier heights, and spectroscopic properties. The lion's share …

DFT exchange: sharing perspectives on the workhorse of quantum chemistry and materials science

AM Teale, T Helgaker, A Savin, C Adamo… - Physical chemistry …, 2022 - pubs.rsc.org
In this paper, the history, present status, and future of density-functional theory (DFT) is
informally reviewed and discussed by 70 workers in the field, including molecular scientists …

Robust and efficient implicit solvation model for fast semiempirical methods

S Ehlert, M Stahn, S Spicher… - Journal of Chemical …, 2021 - ACS Publications
We present a robust and efficient method to implicitly account for solvation effects in modern
semiempirical quantum mechanics and force fields. A computationally efficient yet accurate …

Efficient quantum chemical calculation of structure ensembles and free energies for nonrigid molecules

S Grimme, F Bohle, A Hansen, P Pracht… - The Journal of …, 2021 - ACS Publications
The application of quantum chemical, automatic multilevel modeling workflows for the
determination of thermodynamic (eg, conformation equilibria, partition coefficients, p K a …

GEOM, energy-annotated molecular conformations for property prediction and molecular generation

S Axelrod, R Gomez-Bombarelli - Scientific Data, 2022 - nature.com
Abstract Machine learning (ML) outperforms traditional approaches in many molecular
design tasks. ML models usually predict molecular properties from a 2D chemical graph or a …

Automated molecular cluster growing for explicit solvation by efficient force field and tight binding methods

S Spicher, C Plett, P Pracht, A Hansen… - Journal of Chemical …, 2022 - ACS Publications
An automated and broadly applicable workflow for the description of solvation effects in an
explicit manner is introduced. This method, termed quantum cluster growth (QCG), is based …

Assessing density functional theory for chemically relevant open-shell transition metal reactions

LR Maurer, M Bursch, S Grimme… - Journal of Chemical …, 2021 - ACS Publications
Due to the principle lack of systematic improvement possibilities of density functional theory,
careful assessment of the performance of density functional approximations (DFAs) on well …

Polyoxometalate‐soft matter composite materials: design strategies, applications, and future directions

JH Kruse, M Langer, I Romanenko… - Advanced functional …, 2022 - Wiley Online Library
Molecular metal oxides or polyoxometalates (POMs) offer unrivaled properties in areas
ranging from catalysis and energy conversion through to molecular electronics, biomimetics …

The predictive power of exact constraints and appropriate norms in density functional theory

AD Kaplan, M Levy, JP Perdew - Annual Review of Physical …, 2023 - annualreviews.org
Ground-state Kohn-Sham density functional theory provides, in principle, the exact ground-
state energy and electronic spin densities of real interacting electrons in a static external …