Approximately one-half of all known protein crystal structures in the protein data bank (PDB)
contain metal ion cofactors, which play vital roles in charge neutralization, structure, and …

▪ Abstract Electron transmission through molecules and molecular interfaces has been a
subject of intensive research due to recent interest in electron-transfer phenomena …

We investigate the polariton-mediated electron transfer reaction in a model system with
analytic rate constant theory and direct quantum dynamical simulations. We demonstrate …

Electrons have so little mass that in less than a second they can tunnel through potential
energy barriers that are several electron-volts high and several nanometers wide. Electron …

1. History 3422. Activation barriers 3432.1 Redox potentials 3442.2 Reorganization energy
3443. Electronic coupling 3454. Ru-modified proteins 3484.1 Reorganization energy …

Proton-coupled electron transfer (PCET) underpins energy conversion in biology. PCET may
occur with the unidirectional or bidirectional transfer of a proton and electron and may …

The rate of long-distance electron transfer in proteins rapidly decreases with distance, which
is indicative of an electron tunneling process. Calculations predict that the distance …

Several types of microactuators have been fabricated, from simple paddles to self-
assembling and-disassembling cubes. Conducting bilayers made of a layer of polymer and …

The electron-transfer (ET) reactions of metallo-proteins are potentially far more complex than
those of small molecules. Thestructural intricacies of proteins are largely responsible for the …

The crystal structure of manganese peroxidase (MnP) from the lignin-degrading
basidiomycetous fungus Phanerochaete chrysosporium has been solved using molecular …