A Strategy for Selective Catalytic B–H Functionalization of o-Carboranes

Z Qiu, Z **e - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Carboranes are a class of polyhedral carbon–boron molecular clusters
featuring three-dimensional aromaticity, which are often considered as 3D analogues of …

Controlled functionalization of o-carborane via transition metal catalyzed B–H activation

Y Quan, Z **e - Chemical Society Reviews, 2019 - pubs.rsc.org
Carboranes, a class of carbon–boron molecular clusters, are often viewed as three-
dimensional analogues of benzene. They are finding increasing applications as useful …

Redox-switchable carboranes for uranium capture and release

M Keener, C Hunt, TG Carroll, V Kampel… - Nature, 2020 - nature.com
Abstract The uranyl ion (UO22+; U (vi) oxidation state) is the most common form of uranium
found in terrestrial and aquatic environments and is a central component in nuclear fuel …

Boron science

NS Hosmane - New technologies and applications, 2011 - api.taylorfrancis.com
What is boron? The question itself may not seem very significant to many people. Their
introduction to the word “boron” could come as the butt of a joke. Conan O'Brien made jokes …

Boron clusters in luminescent materials

S Mukherjee, P Thilagar - Chemical Communications, 2016 - pubs.rsc.org
In recent times, luminescent materials with tunable emission properties have found
applications in almost all aspects of modern material sciences. Any discussion on the recent …

Recent Advances in Transition Metal-Catalyzed Selective BH Functionalization of o-Carboranes

YK Au, Z **e - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
Carboranes are a class of carbon-boron molecular clusters, possessing extraordinary
characteristics including three-dimensional aromaticity conjugated by σ-bonds, icosahedral …

Cyclopentadienyl− carboranyl hybrid compounds: a new class of versatile ligands for organometallic chemistry

Z **e - Accounts of chemical research, 2003 - ACS Publications
A new class of organic− inorganic hybrid compounds bearing a cyclic π-ligand, an
icosahedral carborane moiety, and a bridging group has been developed. These are very …

Iridium Catalyzed Regioselective Cage Boron Alkenylation of o-Carboranes via Direct Cage B–H Activation

Y Quan, Z **e - Journal of the American Chemical Society, 2014 - ACS Publications
Iridium catalyzed alkyne hydroboration with o-carborane cage B–H has been achieved,
leading to the formation of a series of 4-B-alkenylated-o-carborane derivatives in high yields …

Ir-catalyzed enantioselective B−H alkenylation for asymmetric synthesis of chiral-at-cage o‑carboranes

R Cheng, J Zhang, H Zhang, Z Qiu, Z **e - Nature Communications, 2021 - nature.com
The asymmetric synthesis of chiral-at-cage o-carboranes, whose chirality is associated with
the substitution patterns on the polyhedron, is of great interest as the icosahedral …

Transition metal− carboryne complexes: synthesis, bonding, and reactivity

Z Qiu, S Ren, Z **e - Accounts of chemical research, 2011 - ACS Publications
The construction and transformation of metal− carbon (M− C) bonds constitute the central
themes of organometallic chemistry. Most of the work in this field has focused on traditional …