Life in Multi-Extreme Environments: Brines, Osmotic and Hydrostatic Pressure─ A Physicochemical View

JM Knop, S Mukherjee, MW Jaworek… - Chemical …, 2022 - ACS Publications
Elucidating the details of the formation, stability, interactions, and reactivity of biomolecular
systems under extreme environmental conditions, including high salt concentrations in …

Supercritical water is not hydrogen bonded

P Schienbein, D Marx - Angewandte Chemie International …, 2020 - Wiley Online Library
Abstract Thinking about water is inextricably linked to hydrogen bonds, which are highly
directional in character and determine the unique structure of water, in particular its …

Nanoconfinement effects on water in narrow graphene-based slit pores as revealed by THz spectroscopy

S Ruiz-Barragan, F Sebastiani, P Schienbein… - Physical Chemistry …, 2022 - pubs.rsc.org
The properties of water at interfaces have long been known to differ from those of bulk water
in many distinctive ways. More recently, specific confinement effects different from mere …

An isolated water droplet in the aqueous solution of a supramolecular tetrahedral cage

F Sebastiani, TA Bender, S Pezzotti… - Proceedings of the …, 2020 - National Acad Sciences
Water under nanoconfinement at ambient conditions has exhibited low-dimensional ice
formation and liquid–solid phase transitions, but with structural and dynamical signatures …

Generating interstitial water within the persisting tetrahedral H-bond network explains density increase upon compressing liquid water

M Förster, N Ukoji, CJ Sahle, J Niskanen… - Proceedings of the …, 2024 - pnas.org
Despite its ubiquitous nature, the atomic structure of water in its liquid state is still
controversially debated. We use a combination of X-ray Raman scattering spectroscopy in …

Terahertz spectroscopy of thick and diluted water solutions

F Novelli - Optics Express, 2024 - opg.optica.org
While bright terahertz sources are used to perform nonlinear experiments, they can be
advantageous for high-precision linear measurements of opaque samples. By placing the …

Solvation Properties of Neutral Gold Species in Supercritical Water Studied By THz Spectroscopy

J Noetzel, P Schienbein, H Forbert… - Angewandte Chemie …, 2024 - Wiley Online Library
Supercritical water provides distinctly different solvation properties compared to what is
known from liquid water. Despite its prevalence deep in the Earth's crust and its role in …

Water structure modification by d-(+)-glucose at different concentrations and temperatures-effect of mutarotation

M Hossain, N Chowdhury, A Atahar, MABH Susan - RSC advances, 2023 - pubs.rsc.org
Water structure modification by carbohydrates is essential both in chemistry and life
processes and in particular, molecular level interaction of glucose with water is very …

Solvation of small gold clusters in supercritical water

J Noetzel, P Schienbein, H Forbert, D Marx - Journal of Molecular Liquids, 2022 - Elsevier
Solvation in supercritical water features fascinating properties such as the selective
dissolution or precipitation of non-polar versus polar species. This is known since long to …

Evidence of a low–high density turning point in liquid water at ordinary temperature under pressure: a molecular dynamics study

M Pagliai, M Macchiagodena, P Procacci… - The Journal of …, 2019 - ACS Publications
Water has a fundamental role in important processes spanning a wide range of pressure
and temperature conditions. Knowledge of structural, dynamic and thermodynamic …