Toward a first-principles framework for predicting collective properties of electrolytes
Conspectus Given the universal importance of electrolyte solutions, it is natural to expect
that we have a nearly complete understanding of the fundamental properties of these …
that we have a nearly complete understanding of the fundamental properties of these …
Formation, chemical evolution and solidification of the dense liquid phase of calcium (bi) carbonate
Metal carbonates, which are ubiquitous in the near-surface mineral record, are a major
product of biomineralizing organisms and serve as important targets for capturing …
product of biomineralizing organisms and serve as important targets for capturing …
[HTML][HTML] The known-unknowns of anomalous underscreening in concentrated electrolytes
Electrolytes are central to life and technology but lack complete understanding. Recent
experiments with highly concentrated electrolytes have revealed electrostatic decay lengths …
experiments with highly concentrated electrolytes have revealed electrostatic decay lengths …
Correlation length in concentrated electrolytes: Insights from all-atom molecular dynamics simulations
We study the correlation length of the charge–charge pair correlations in concentrated
electrolyte solutions by means of all-atom, explicit-solvent molecular dynamics simulations …
electrolyte solutions by means of all-atom, explicit-solvent molecular dynamics simulations …
Electrostatic screening length in concentrated salt solutions
P Gaddam, W Ducker - Langmuir, 2019 - ACS Publications
Thin films (0–30 nm) of very concentrated aqueous monovalent salt solutions (2–10 M of
LiCl, NaCl, and CsCl) were examined to determine how ionic strength affects the screening …
LiCl, NaCl, and CsCl) were examined to determine how ionic strength affects the screening …
Screening length for finite-size ions in concentrated electrolytes
The classical Debye-Hückel (DH) theory clearly accounts for the origin of screening in
electrolyte solutions and works rather well for dilute electrolyte solutions. While the Debye …
electrolyte solutions and works rather well for dilute electrolyte solutions. While the Debye …
Nanocrystals in molten salts and ionic liquids: experimental observation of ionic correlations extending beyond the Debye length
V Kamysbayev, V Srivastava, NB Ludwig… - ACS …, 2019 - ACS Publications
The nature of the interface between the solute and the solvent in a colloidal solution has
attracted attention for a long time. For example, the surface of colloidal nanocrystals (NCs) is …
attracted attention for a long time. For example, the surface of colloidal nanocrystals (NCs) is …
Structure and anomalous underscreening in ethylammonium nitrate solutions confined between two mica surfaces
The observation of long-range interactions across ionic liquids and highly concentrated
electrolytes, extending far beyond the Debye–Hückel prediction and beyond the range …
electrolytes, extending far beyond the Debye–Hückel prediction and beyond the range …
[HTML][HTML] Detecting underscreening and generalized Kirkwood transitions in aqueous electrolytes
We establish the connection between the measured small angle x-ray scattering signal and
the charge–charge correlations underlying Kirkwood transitions (KTs) in 1: 1, 2: 1, and 3: 1 …
the charge–charge correlations underlying Kirkwood transitions (KTs) in 1: 1, 2: 1, and 3: 1 …
Phase transitions and electrochemical properties of ionic liquids and ionic liquid—Solvent mixtures
Recent advances in studies of ionic liquids (IL) and ionic liquid–solvent mixtures are
reviewed. Selected experimental, simulation, and theoretical results for electrochemical …
reviewed. Selected experimental, simulation, and theoretical results for electrochemical …