Spin-vibronic mechanism for intersystem crossing

TJ Penfold, E Gindensperger, C Daniel… - Chemical …, 2018 - ACS Publications
Intersystem crossing (ISC), formally forbidden within nonrelativistic quantum theory, is the
mechanism by which a molecule changes its spin state. It plays an important role in the …

Photophysics of thermally activated delayed fluorescence molecules

FB Dias, TJ Penfold, AP Monkman - Methods and applications in …, 2017 - iopscience.iop.org
Thermally activated delayed fluorescence (TADF) has recently emerged as one of the most
attractive methods for harvesting triplet states in metal-free organic materials for application …

Linac coherent light source: The first five years

C Bostedt, S Boutet, DM Fritz, Z Huang, HJ Lee… - Reviews of Modern …, 2016 - APS
A new scientific frontier opened in 2009 with the start of operations of the world's first x-ray
free-electron laser (FEL), the Linac Coherent Light Source (LCLS), at SLAC National …

Ultrafast electron dynamics in solar energy conversion

CS Ponseca Jr, P Chábera, J Uhlig, P Persson… - Chemical …, 2017 - ACS Publications
Electrons are the workhorses of solar energy conversion. Conversion of the energy of light to
electricity in photovoltaics, or to energy-rich molecules (solar fuel) through photocatalytic …

Sub-50-fs photoinduced spin crossover in [Fe(bpy)3]2+

G Auböck, M Chergui - Nature chemistry, 2015 - nature.com
It is known that excitation by visible light of the singlet metal-to-ligand charge-transfer
(1MLCT) states of Fe (ii) complexes leads to population of the lowest-lying high-spin quintet …

Improved transition metal photosensitizers to drive advances in photocatalysis

D Kim, VQ Dang, TS Teets - Chemical Science, 2024 - pubs.rsc.org
To function effectively in a photocatalytic application, a photosensitizer's light absorption,
excited-state lifetime, and redox potentials, both in the ground state and excited state, are …

Tracking excited-state charge and spin dynamics in iron coordination complexes

W Zhang, R Alonso-Mori, U Bergmann, C Bressler… - Nature, 2014 - nature.com
Crucial to many light-driven processes in transition metal complexes is the absorption and
dissipation of energy by 3 d electrons,,,. But a detailed understanding of such non …

Fe N-Heterocyclic Carbene Complexes as Promising Photosensitizers

Y Liu, P Persson, V Sundstrom… - Accounts of chemical …, 2016 - ACS Publications
Conspectus The photophysics and photochemistry of transition metal complexes (TMCs)
has long been a hot field of interdisciplinary research. Rich metal-based redox processes …

Direct observation of ultrafast collective motions in CO myoglobin upon ligand dissociation

TRM Barends, L Foucar, A Ardevol, K Nass, A Aquila… - Science, 2015 - science.org
The hemoprotein myoglobin is a model system for the study of protein dynamics. We used
time-resolved serial femtosecond crystallography at an x-ray free-electron laser to resolve …

[LIBRO][B] Highly efficient OLEDs: Materials based on thermally activated delayed fluorescence

H Yersin - 2019 - books.google.com
The essential resource that offers a comprehensive understanding of OLED optimizations
Highly Efficient OLEDs. Materials Based on Thermally Activated Delayed Fluorescence …