Fully biodegradable and biorenewable ternary blends from polylactide, poly (3-hydroxybutyrate-co-hydroxyvalerate) and poly (butylene succinate) with balanced …

K Zhang, AK Mohanty, M Misra - ACS applied materials & …, 2012 - ACS Publications
A ternary blend of entirely biodegradable polymers, namely polylactide (PLA), poly (3-
hydroxybutyrate-co-hydroxyvalerate)(PHBV), and poly (butylene succinate)(PBS), was first …

Interfacial mobility scale determines the scale of collective motion and relaxation rate in polymer films

PZ Hanakata, JF Douglas, FW Starr - Nature communications, 2014 - nature.com
Thin polymer films are ubiquitous in manufacturing and medical applications, and there has
been intense interest in how film thickness and substrate interactions influence film …

Polymers under nanoconfinement: where are we now in understanding local property changes?

CB Roth - Chemical Society Reviews, 2021 - pubs.rsc.org
Polymers are increasingly being used in applications with nanostructured morphologies
where almost all polymer molecules are within a few tens to hundreds of nanometers from …

Relaxation behavior of polymer thin films: Effects of free surface, buried interface, and geometrical confinement

B Li, S Zhang, JS Andre, Z Chen - Progress in Polymer Science, 2021 - Elsevier
The glass transition temperature (T g) of polymer thin films, one of the most important
parameters to characterize the relaxation behavior of polymer chains in a thin film, has been …

Formation mechanism of high-density, flattened polymer nanolayers adsorbed on planar solids

N Jiang, J Shang, X Di, MK Endoh, T Koga - Macromolecules, 2014 - ACS Publications
Thermal annealing is one of the most indispensable polymer fabrication processes and
plays essential roles in controlling morphologies and properties of polymeric materials. We …

Impact of an irreversibly adsorbed layer on local viscosity of nanoconfined polymer melts

T Koga, N Jiang, P Gin, MK Endoh, S Narayanan… - Physical review …, 2011 - APS
We report the origin of the effect of nanoscale confinement on the local viscosity of
entangled polystyrene (PS) films at temperatures far above the glass transition temperature …

Effect of nanostructure on the thermal glass transition and physical aging in polymer materials

D Cangialosi, A Alegria, J Colmenero - Progress in Polymer Science, 2016 - Elsevier
We review the recent activity aiming to clarify glassy dynamics in nanostructured polymer
glasses, in particular thin films, nanocomposites and nanospheres. Special emphasis is …