Recent advances in lanthanide coordination polymers and clusters with magnetocaloric effect or single-molecule magnet behavior

JJ Hu, Y Peng, SJ Liu, HR Wen - Dalton Transactions, 2021 - pubs.rsc.org
Molecular magnetorefrigerant materials for low-temperature magnetic refrigeration and
single-molecule magnets for high-density information storage and quantum computing have …

Two Pairs of Homochiral Parallelogram-like Dy4 Cluster Complexes with Strong Magneto-Optical Properties

CM Liu, R Sun, X Hao, BW Wang - Inorganic Chemistry, 2023 - ACS Publications
Two pairs of homochiral Dy (III) tetranuclear cluster complexes derived from (+)/(−)-3-
trifluoroacetyl camphor (D-Htfc/L-Htfc),[Dy4 (OH) 2 (L1) 4 (D-tfc) 2 (DMF) 2]· 4DMF (D …

Heterometallic 3d–4f single molecule magnets containing diamagnetic metal ions

A Chakraborty, J Goura, P Kalita, A Swain… - Dalton …, 2018 - pubs.rsc.org
Molecular nano magnets such as single-molecule magnets (SMMs) are a class of
coordination complexes with numerous potential applications such as information storage …

The role of 3d–4f exchange interaction in SMM behaviour and magnetic refrigeration of carbonato bridged Cu II2 Ln III2 (Ln= Dy, Tb and Gd) complexes of an …

S Maity, A Mondal, S Konar, A Ghosh - Dalton Transactions, 2019 - pubs.rsc.org
The strategic design and synthesis of a new Cu (II) complex,[CuL](1) of an asymmetrically
dicondensed N2O4 donor ligand (where H2L= N-3-ethoxysalicylidene-N′-3 …

Influence of the Different Types of Auxiliary Noncarboxylate Organic Ligands on the Topologies and Magnetic Relaxation Behavior of Zn–Dy Heterometallic Single …

HS Wang, K Zhang, J Wang, ZB Hu, Z Zhang… - Inorganic …, 2021 - ACS Publications
In this work, we first synthesized a Zn–Dy complex,[Zn6Dy2 (L) 6 (tea) 2 (CH3OH) 2]·
6CH3OH· 8H2O (H2L= N-3-methoxysalicylidene-2-amino-3-hydroxypyridine, teaH3 …

The first exploration of coordination chemistry using a methyl substituted o-vanillin based ligand: an example starting with Dy 4/Zn 2 Dy 2 systems displaying slow …

A Panja, Z Jagličić, R Herchel, P Brandão… - New Journal of …, 2022 - pubs.rsc.org
The literature has witnessed the exceptionally rich coordination chemistry, ranging from
monomeric species to coordination polymers, generated by the Schiff base ligands derived …

Enhancement of magnetic relaxation properties with 3d diamagnetic cations in [Zn II Ln III] and [Ni II Ln III], Ln III= Kramers lanthanides

J Mayans, Q Saez, M Font-Bardia, A Escuer - Dalton Transactions, 2019 - pubs.rsc.org
Employing the chiral bi-compartmental Schiff-base ligand H2L obtained from the
condensation of (RR) or (SS)-1, 2-diphenyl-ethylenediamine and o-vanillin, we report the …

Utilization of diamagnetic Zn (II) ion to boost the anisotropic nature of Ln (III) ion in heterodinuclear Zn (II)–Ln (III) single‐molecule magnets

S Roy, P Shukla, R Kumar, SC Sahoo… - Applied …, 2022 - Wiley Online Library
A series of dimetallic ZnII–LnIII compounds of general formulae [LnZn (L) 3 (NO3) 2]·
2CH3OH (LnIII= DyIII (1), TbIII (2), GdIII (3)) was prepared by stepwise reaction of …

Synthesis, structure and magnetic properties of lanthanum (III) and other lanthanide (III) complexes with zinc (II)-salen type metalloligands: A review

P Middya, S Chattopadhyay - Inorganica Chimica Acta, 2024 - Elsevier
Salen-type compartmental ligands, prepared by the 1: 2 condensation of a diamine and a
salicylaldehyde derivative, have been used in the synthesis of a variety of heretonuclear …

Two types of Ln 2 Cu 2 hydroxo-trimethylacetate complexes with 0D and 1D motifs: synthetic features, structural differences, and slow magnetic relaxation

AA Bovkunova, ES Bazhina, IS Evstifeev… - Dalton …, 2021 - pubs.rsc.org
Two series of heterometallic LnIII–CuII compounds containing a butterfly-like tetranuclear
metal core were synthesized and characterized by X-ray diffraction and magnetometry. The …