Late transition metal-catalyzed hydroamination and hydroamidation

L Huang, M Arndt, K Gooßen, H Heydt… - Chemical …, 2015 - ACS Publications
This Review examines recent developments in late transition metal-catalyzed
hydroamination and-amidation reactions. A hydroamination is a reaction in which an N− H …

Transition metal vinylidene-and allenylidene-mediated catalysis in organic synthesis

SW Roh, K Choi, C Lee - Chemical reviews, 2019 - ACS Publications
With their mechanistic novelty and various modalities of reactivity, transition metal
unsaturated carbene (alkenylidene) complexes have emerged as versatile intermediates for …

Recent advances in the synthesis of indoles from alkynes and nitrogen sources

JSS Neto, G Zeni - Organic Chemistry Frontiers, 2020 - pubs.rsc.org
Transition metal-catalyzed cyclization reactions of unsaturated substrates have become one
of the most important and useful methodologies for the preparation of heterocycles. To this …

[BOOK][B] Advances in heterocyclic chemistry

AR Katritzky - 1997 - books.google.com
Established in 1960, Advances in Heterocyclic Chemistry is the definitive serial in the area--
one of great importance to organic chemists, polymer chemists, and many biological …

Merging NiH catalysis and inner-sphere metal-nitrenoid transfer for hydroamidation of alkynes

X Lyu, J Zhang, D Kim, S Seo… - Journal of the American …, 2021 - ACS Publications
The formal hydroamination/hydroamidation utilizing metal hydride is an appealing synthetic
tool for the construction of valuable nitrogen-containing compounds from unsaturated …

Potassium tert-Butoxide Promoted Intramolecular Arylation via a Radical Pathway

DS Roman, Y Takahashi, AB Charette - Organic letters, 2011 - ACS Publications
Potassium tert-butoxide mediated intramolecular cyclization of aryl ethers, amines, and
amides was efficiently performed under microwave irradiation to provide the corresponding …

Transition metal-catalyzed addition of C-, N-and O-nucleophiles to unactivated C–C multiple bonds

NT Patil, RD Kavthe, VS Shinde - Tetrahedron, 2012 - Elsevier
The additions of various nucleophiles (XeH) to carbonecarbon (CeC) multiple bonds are of
prime importance in synthetic organic chemistry. These essentially simple reactions allow …

Aminoboration: Addition of B–N σ Bonds across C–C π Bonds

E Chong, SA Blum - Journal of the American Chemical Society, 2015 - ACS Publications
This communication demonstrates the first catalytic aminoboration of C–C π bonds by B–N σ
bonds and its application to the synthesis of 3-borylated indoles. The regiochemistry and …

Ruthenium-catalyzed cycloisomerization of 2-alkynylanilides: synthesis of 3-substituted indoles by 1, 2-carbon migration

T Watanabe, Y Mutoh, S Saito - Journal of the American Chemical …, 2017 - ACS Publications
Ruthenium-Catalyzed Cycloisomerization of 2-Alkynylanilides: Synthesis of 3-Substituted
Indoles by 1,2-Carbon Migration | Journal of the American Chemical Society ACS ACS …

Mixed Phosphane η5-CpRuCl(PR3)2 Complexes as Ambifunctional Catalysts for Anti-Markovnikov Hydration of Terminal Alkynes

F Boeck, T Kribber, L **ao… - Journal of the American …, 2011 - ACS Publications
The catalytic activity of [CpRu (L) 2 (MeCN)] PF6 (L= 2-diphenylphosphinopyridine with
bulky groups at C-6) for anti-Markovnikov hydration of terminal alkynes to aldehydes is …