Synthesis, structures and applications of electron-rich polyoxometalates

NI Gumerova, A Rompel - Nature Reviews Chemistry, 2018 - nature.com
Ever since the discovery and development of polyoxometalates (POMs), it has been known
that they can exist in electron-rich reduced forms of different archetypes, structural …

Polyoxometalates in dye-sensitized solar cells

L Chen, WL Chen, XL Wang, YG Li, ZM Su… - Chemical Society …, 2019 - pubs.rsc.org
Dye-sensitized solar cells (DSSCs) are the third generation of photovoltaic cells developed
by Grätzel and O'Regan. They have the characteristics of low cost, simple manufacturing …

Polyoxometalate-functionalized nanocarbon materials for energy conversion, energy storage and sensor systems

Y Ji, L Huang, J Hu, C Streb, YF Song - Energy & Environmental …, 2015 - pubs.rsc.org
Composites based on polyoxometalates (POMs) and nanostructured carbon such as carbon
nanotubes (CNTs) or graphene have attracted widespread attention as they combine the …

Structure, properties and reactivity of polyoxometalates: a theoretical perspective

X López, JJ Carbó, C Bo, JM Poblet - Chemical Society Reviews, 2012 - pubs.rsc.org
In the thematic review dedicated to polyoxometalate (POM) chemistry published in Chemical
Reviews in 1998, no contribution was devoted to theory. This is not surprising because …

Semimetal-functionalised polyoxovanadates

KY Monakhov, W Bensch, P Kögerler - Chemical Society Reviews, 2015 - pubs.rsc.org
Polyoxovanadates (POVs), known for their wide applicability and relevance in chemical,
physical and biological sciences, are a subclass of polyoxometalates and usually self …

Progress and challenges in polyoxometalate-based catalysis and catalytic materials chemistry

CL Hill - Journal of Molecular Catalysis A: Chemical, 2007 - Elsevier
The impact of early transition-metal oxygen-anion cluster (polyoxometalate or “POM”)
geometric and electronic structural properties on POM-based catalysis is addressed. Three …

Strategies to explore and develop reversible redox reactions of Li–S in electrode architectures using silver-polyoxometalate clusters

JC Ye, JJ Chen, RM Yuan, DR Deng… - Journal of the …, 2018 - ACS Publications
Investigations of the Ag (I)-substituted Keggin K3 [H3AgIPW11O39] as a bifunctional Lewis
acidic and basic catalyst are reported that explore the stabilization of Li2Sn moieties so that …

Polyoxometalate–reduced graphene oxide hybrid catalyst: synthesis, structure, and electrochemical properties

Y Kim, S Shanmugam - ACS applied materials & interfaces, 2013 - ACS Publications
The deposition of polyoxometalate (POM) on chemically reduced graphene oxide sheets
was carried out through electron transfer interaction and electrostatic interaction between …

Super-reduced polyoxometalates: excellent molecular cluster battery components and semipermeable molecular capacitors

Y Nishimoto, D Yokogawa, H Yoshikawa… - Journal of the …, 2014 - ACS Publications
Theoretical investigations are presented on the molecular and electronic structure changes
that occur as α-Keggin-type polyoxometalate (POM3–) clusters [PM12O40] 3–(M= Mo, W) …

On the preferences of five-membered chelate rings in coordination chemistry: insights from the Cambridge Structural Database and theoretical calculations

M Bazargan, M Mirzaei, A Franconetti… - Dalton Transactions, 2019 - pubs.rsc.org
The purpose of this review is to give an overview of three important N-bidentate ligands: 1,
10-phenanthroline (phen), 2, 2′-bipyridine (bpy), and ethylenediamine (en). We have not …