Sustainable Copolymer Synthesis from Carbon Dioxide and Butadiene
Carbon dioxide (CO2) has long been recognized as an ideal C1 feedstock comonomer for
producing sustainable materials because it is renewable, abundant, and cost-effective …
producing sustainable materials because it is renewable, abundant, and cost-effective …
Advances in the synthesis of copolymers from carbon dioxide, dienes, and olefins
Conspectus Carbon dioxide (CO2) has long been considered a sustainable comonomer for
polymer synthesis due to its abundance, easy availability, and low toxicity. Polymer …
polymer synthesis due to its abundance, easy availability, and low toxicity. Polymer …
A Topology‐Defined Polyester Elastomer from CO2 and 1,3‐Butadiene: A One‐Pot‐One‐Step “Scrambling Polymerizations” Strategy
K Chen, Z Zhu, T Bai, Y Mei, T Shen… - Angewandte Chemie …, 2022 - Wiley Online Library
It is significant and challenging to use CO2 to produce polymeric materials, especially with
olefins. Here, a novel strategy named “scrambling polymerizations” is designed and …
olefins. Here, a novel strategy named “scrambling polymerizations” is designed and …
3-Ethyl-6-vinyltetrahydro-2 H-pyran-2-one (EVP): a versatile CO 2-derived lactone platform for polymer synthesis
3-Ethyl-6-vinyltetrahydro-2H-pyran-2-one (EVP) is a CO2-derived lactone synthesized via
Pd-catalyzed telomerization of butadiene. As EVP is 28.9% by weight CO2, it has received …
Pd-catalyzed telomerization of butadiene. As EVP is 28.9% by weight CO2, it has received …
Bifunctional and recyclable polyesters by chemoselective ring-opening polymerization of a δ-lactone derived from CO2 and butadiene
J Zhang, L Jiang, S Liu, J Shen, P Braunstein… - Nature …, 2024 - nature.com
When aiming at the direct use of CO2 for the preparation of advanced/value-added
materials, the synthesis of CO2/olefin copolymers is very appealing but challenging. The δ …
materials, the synthesis of CO2/olefin copolymers is very appealing but challenging. The δ …
How to Open the Ring of a Di‐ene‐Substituted‐δ‐Valerolactone: From Carbon Dioxide and 1, 3‐Butadiene to Functional Polyesters
K Chen, Y Mei, Z Zhang, J Ling, X Ni - ChemPlusChem, 2023 - Wiley Online Library
As a substituted‐δ‐valerolactone, α‐ethylidene‐δ‐vinyl‐δ‐valerolactone (EVL) provides a
method of utilizing carbon dioxide with 1, 3‐butadiene to produce functional polymers. Its di …
method of utilizing carbon dioxide with 1, 3‐butadiene to produce functional polymers. Its di …
The Divergent Reactivity of Lactones Derived from Butadiene and Carbon Dioxide in Macromolecular Synthesis
JM Eagan - Macromolecular Rapid Communications, 2023 - Wiley Online Library
The catalytic conversion of carbon dioxide and 1, 3‐butadiene into unsaturated lactone
monomers provides an efficient route for converting sustainable carbon feedstocks into …
monomers provides an efficient route for converting sustainable carbon feedstocks into …
Transformation of Styrene into Biodegradable Polymer through In Situ Epoxidation-Copolymerization Using Tandem Polymeric Catalysts
R Zhang, S Liu, C Zhuo, H Cao, X Wang - Macromolecules, 2023 - ACS Publications
The petroleum-based vinyl monomers have advanced society as the essential feedstock of
synthetic polymers, producing over 150 million tons of attractive polymers annually …
synthetic polymers, producing over 150 million tons of attractive polymers annually …
Random Terpolymer of Carbon Dioxide, Butadiene and Epoxides: Synthesis, Functionalization and Degradability
Z Wang, W Zheng, S Yue, K Chen… - Chinese Journal of …, 2024 - Wiley Online Library
Comprehensive Summary The utilization of carbon dioxide (CO2) as a C1 feedstock is
consistently attractive, especially in the preparation of sustainable polymeric materials. In …
consistently attractive, especially in the preparation of sustainable polymeric materials. In …
Intra- and Intermolecular Hydrogen Bonding in Miscible Blends of CO2/Epoxy Cyclohexene Copolymer with Poly(Vinyl Phenol)
In this study, we synthesized a poly (cyclohexene carbonate)(PCHC) through alternative ring-
opening copolymerization of CO2 with cyclohexene oxide (CHO) mediated by a binary …
opening copolymerization of CO2 with cyclohexene oxide (CHO) mediated by a binary …