Energy-related small molecule activation reactions: oxygen reduction and hydrogen and oxygen evolution reactions catalyzed by porphyrin-and corrole-based …

W Zhang, W Lai, R Cao - Chemical reviews, 2017 - ACS Publications
Globally increasing energy demands and environmental concerns related to the use of fossil
fuels have stimulated extensive research to identify new energy systems and economies that …

Electronic structure of corrole derivatives: insights from molecular structures, spectroscopy, electrochemistry, and quantum chemical calculations

A Ghosh - Chemical Reviews, 2017 - ACS Publications
Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

Fighting cancer with corroles

RD Teo, JY Hwang, J Termini, Z Gross… - Chemical …, 2017 - ACS Publications
Corroles are exceptionally promising platforms for the development of agents for
simultaneous cancer-targeting imaging and therapy. Depending on the element chelated by …

Superoxide dismutase mimics: chemistry, pharmacology, and therapeutic potential

I Batinić-Haberle, JS Rebouças… - Antioxidants & redox …, 2010 - liebertpub.com
Oxidative stress has become widely viewed as an underlying condition in a number of
diseases, such as ischemia–reperfusion disorders, central nervous system disorders …

Strategies for corrole functionalization

JFB Barata, MGPMS Neves, MAF Faustino… - Chemical …, 2017 - ACS Publications
This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …

Aura of corroles

I Aviv‐Harel, Z Gross - Chemistry–A European Journal, 2009 - Wiley Online Library
Corroles display distinctive structural, spectroscopic, and photophysical properties, as well
as some exceptional chemical reactivities that are not shared by other molecules. In …

Hydrogen evolution catalyzed by corrole-chelated nickel complexes, characterized in all catalysis-relevant oxidation states

QC Chen, S Fite, N Fridman, B Tumanskii… - ACS …, 2022 - ACS Publications
Designing catalysts that are not based on precious metals remains a major research priority
worldwide, particularly for the feasible production of hydrogen gas. Given the increasing …

Milestones and most recent advances in Corrole's Science and Technology

A Mahammed, Z Gross - Journal of the American Chemical …, 2023 - ACS Publications
The renaissance in corrole chemistry is strongly correlated with synthetic breakthroughs that
started in 1999, regarding the one-pot rather than multistep syntheses of this heme-like N4 …

Synthesis and characterization of germanium, tin, phosphorus, iron, and rhodium complexes of tris (pentafluorophenyl) corrole, and the utilization of the iron and …

L Simkhovich, A Mahammed… - … –A European Journal, 2001 - Wiley Online Library
Abstract The germanium (iv), tin (iv), and phosphorus (v) complexes of tris
(pentafluorophenyl) corrole were prepared and investigated by electrochemistry for …

Corrole-based applications

I Aviv, Z Gross - Chemical Communications, 2007 - pubs.rsc.org
Despite of the many similarities between corroles and porphyrins, the chemistry of the former
remained undeveloped for decades because of severe synthetic obstacles. The recent …