Electronic structure alternatives in nitrosylruthenium complexes

GK Lahiri, W Kaim - Dalton Transactions, 2010 - pubs.rsc.org
Coordination compounds [Ru (NO) Ln] containing an electro-active metal and potentially
non-innocent ligands NO (and L) can have ground state electronic structures formulated as …

Visible and NIR Light Assistance of the N2 Reduction to NH3 Catalyzed by Cs-promoted Ru Nanoparticles Supported on Strontium Titanate

Y Peng, J Albero, A Franconetti, P Concepción… - ACS …, 2022 - ACS Publications
NH3 production accounts for more than 1% of the total CO2 emissions and is considered
one of the most energy-intensive industrial processes currently (T> 400° C and P> 80 bars) …

Near-IR light-induced photorelease of nitric oxide (NO) on ruthenium nitrosyl complexes: formation, reactivity, and biological effects

B Giri, T Saini, S Kumbhakar, A Muley, A Misra… - Dalton …, 2020 - pubs.rsc.org
Polypyridyl backbone nitrosyl complexes of ruthenium with the molecular framework [RuII
(antpy)(bpy) NO+/˙] n+ [4](PF6) 3 (n= 3),[4](PF6) 2 (n= 2), where antpy= 4′-(anthracene-9 …

Nitric oxide (NO) photo-release in a series of ruthenium–nitrosyl complexes: new experimental insights in the search for a comprehensive mechanism

M Roose, M Tassé, PG Lacroix, I Malfant - New Journal of Chemistry, 2019 - pubs.rsc.org
A series of four ruthenium (II) complexes built from the [Ru (terpy)(bipy)(NO)] 3+ core (terpy
is 2, 2′: 6′, 2′′-terpyridine and bipy is 2, 2′-bipyridine) are investigated. They differ by …

Photorelease of nitric oxide (NO) on ruthenium nitrosyl complexes with phenyl substituted terpyridines

S Amabilino, M Tasse, PG Lacroix… - New Journal of …, 2017 - pubs.rsc.org
We investigated the influence of the nature of the substituent on the 4′-position of
terpyridine ligands and the geometry around the metal ion on the photosensitization of …

Electronic structure and multicatalytic features of redox-active bis (arylimino) acenaphthene (BIAN)-derived ruthenium complexes

A Singha Hazari, R Ray, MA Hoque… - Inorganic Chemistry, 2016 - ACS Publications
The article examines the newly designed and structurally characterized redox-active BIAN-
derived [Ru (trpy)(R-BIAN) Cl] ClO4 ([1a] ClO4–[1c] ClO4),[Ru (trpy)(R-BIAN)(H2O)](ClO4) 2 …

Transition metal complexes as solar photocatalysts in the environment: A short review of recent development

Z Stasicka - Advances in inorganic chemistry, 2011 - Elsevier
The role of photocatalysis by transition metal complexes in the environment is reviewed, and
its influence on composition of the environmental compartments, transport between them …

Photo controlled release of nitric oxide (NO) from amphiphilic and nanoscale vesicles based ruthenium nitrosyl complex: NO release and cytotoxicity studies

N Sharma, P Arjunan, S Marepally, N Jain… - … of Photochemistry and …, 2022 - Elsevier
Nitric oxide (NO) is an important gaseous signaling molecule. Precise spatiotemporal control
release of NO for therapeutic applications is still challenging. We report herein a new …

Nitric oxide photo-release from a ruthenium nitrosyl complex with a 4, 4′-bisfluorenyl-2, 2′-bipyridine ligand

M Roose, I Sasaki, V Bukhanko, S Mallet-Ladeira… - Polyhedron, 2018 - Elsevier
A ruthenium nitrosyl complex of formula [Ru II (terpy)(F2B)(NO)](PF 6) 3, where terpy stands
for 2, 2′: 6′, 2 ″-terpyridine and F2B for 4, 4′-bis (9, 9′-dibutyl-9H-fluoren-2-yl)-2, 2 …

Formation, reactivity, photorelease, and scavenging of NO in ruthenium nitrosyl complexes

B Giri, S Kumbhakar, KK Selvan, A Muley, S Maji - Inorganica Chimica Acta, 2020 - Elsevier
The two newly designed nitrosyl complexes with Enemark–Feltham notation {RuNO} 6 and
{RuNO} 7 configurations have been isolated as the perchlorate salts in the molecular …