In Situ Synchrotron X‐ray Diffraction Studies of the Mechanochemical Synthesis of ZnS from its Elements

H Petersen, S Reichle, S Leiting… - … A European Journal, 2021 - Wiley Online Library
Mechanochemistry, as a synthesis tool for inorganic materials, became an ever‐growing
field in material chemistry. The direct energy transfer by collision of the educts with the …

Flux Method Growth and Structural Analysis of Two Tetravalent Uranium Orthophosphate Single Crystals, Cs2UIV(PO4)2 and Isostructural Cs2(UIV0.75CeIV0.25)(PO4) …

Y Wang, X Zhang, L Li, T Bo, L Zhang - Inorganic Chemistry, 2024 - ACS Publications
Two novel uranium (IV) orthophosphate framework compounds were obtained by the high-
temperature flux method in CsCl-CsF eutectic salt. Cs2UIV (PO4) 2 (1) and isostructural Cs2 …

Cerium (IV) orthophosphates

TO Kozlova, AE Baranchikov, VK Ivanov - Russian Journal of Inorganic …, 2021 - Springer
The review analyzes the data on the composition, structure, and properties of amorphous
and crystalline cerium (IV) orthophosphates published between 1882 and 2020. The review …

Preparation and crystal structure of K 2 Ce (PO 4) 2: a new complex phosphate of Ce (IV) having structure with one-dimensional channels

S Bevara, SN Achary, SJ Patwe, AK Sinha… - Dalton …, 2016 - pubs.rsc.org
In this manuscript we report crystal structure of a new complex binary phosphate K2Ce4+
(PO4) 2 in K2O–P2O5–CeO2 system prepared by solid state reaction at moderate …

Phase Transformation, Vibrational and Electronic Properties of K2Ce(PO4)2: A Combined Experimental and Theoretical Study

S Bevara, KK Mishra, SJ Patwe, TR Ravindran… - Inorganic …, 2017 - ACS Publications
Herein we report the high-temperature crystal chemistry of K2Ce (PO4) 2 as observed from a
joint in situ variable-temperature X-ray diffraction (XRD) and Raman spectroscopy as well as …

Insights into Structural Diversity and Morphotropic Evolution in A4Th(WO4)4 (A=Li, Na, K, Rb and Cs) Family

Y Yu, B **ao, RA Eichel… - Chemistry–A European …, 2025 - Wiley Online Library
A series of four new thorium tungstates, A4Th (WO4) 4 (A= Li, K, Rb, Cs), were synthesized
using high‐temperature solid‐state method. Structural studies of the materials reveal distinct …

A density-functional theory structural database for discovery of novel actinide waste forms

MS Christian, KA Pace, VV Klepov… - Crystal Growth & …, 2021 - ACS Publications
While high-level nuclear waste is effectively incorporated into borosilicate glasses for
disposal, issues remain for handling transuranic (TRU) elements. Computational methods …

Effects of Te (IV) oxo-anion incorporation into thorium molybdates and tungstates

B **ao, M Klinkenberg, D Bosbach… - Inorganic …, 2015 - ACS Publications
The exploration of phase formation in the Th–Mo/W–Te systems has resulted in four mixed
oxo-anion compounds from high-temperature solid-state reactions: ThWTe2O9, Th …

Cation-Dependent Structural Evolution in A2Th(TVO4)2 (A = Li, Na, K, Rb, Cs; T = P and As) Series

N Yu, VV Klepov, H Schlenz, D Bosbach… - Crystal growth & …, 2017 - ACS Publications
A new alkali thorium phosphate family, A2Th (PO4) 2 (A= Li, Na, K, Rb, Cs), has been
synthesized and systematically investigated. The structural evolution of this new family was …

Structural variations in complex sodium thorium arsenates

Y Hao, EV Alekseev, VV Klepov… - European Journal of …, 2020 - Wiley Online Library
Three new sodium thorium arsenates, Na5Th4 (AsO4) 7 (1), Na5Th (AsO4) 3 (2), and Na4Th
(As2O7) 2 (3) were synthesized via a high temperature route and their structures and optical …