Atom transfer radical polymerization: a mechanistic perspective

F Lorandi, M Fantin… - Journal of the American …, 2022 - ACS Publications
Since its inception, atom transfer radical polymerization (ATRP) has seen continuous
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …

Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications

N Corrigan, K Jung, G Moad, CJ Hawker… - Progress in Polymer …, 2020 - Elsevier
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …

Recyclable cyclic bio-based acrylic polymer via pairwise monomer enchainment by a trifunctional Lewis pair

Y Song, J He, Y Zhang, RA Gilsdorf, EYX Chen - Nature Chemistry, 2023 - nature.com
The existing catalyst/initiator systems and methodologies used for the synthesis of polymers
can access only a few cyclic polymers composed entirely of a single monomer type, and the …

Opportunities, challenges, and pitfalls in making, characterizing, and understanding polymer brushes

CW Pester, HA Klok, EM Benetti - Macromolecules, 2023 - ACS Publications
Polymer brushes have been theoretically described, their behavior under diverse conditions
has been modeled, and their preparation via surface-initiated polymerizations (SIPs) has …

Cyclic polymers: synthesis, characteristics, and emerging applications

C Chen, T Weil - Nanoscale Horizons, 2022 - pubs.rsc.org
Cyclic polymers with a ring-like topology and no chain ends are a unique class of
macromolecules. In the past several decades, significant advances have been made to …

Scaling perspective on dynamics of nanoparticles in polymers: length-and time-scale dependent nanoparticle–polymer coupling

T Ge - Macromolecules, 2023 - ACS Publications
The motion of nanoparticles in a polymer matrix is dictated by the intricate coupling of the
nanoparticles and surrounding polymers. Various length-and time-scale dependent features …

Chemistry-informed macromolecule graph representation for similarity computation, unsupervised and supervised learning

S Mohapatra, J An… - … Learning: Science and …, 2022 - iopscience.iop.org
The near-infinite chemical diversity of natural and artificial macromolecules arises from the
vast range of possible component monomers, linkages, and polymers topologies. This …

Design of materials with supramolecular polymers

TD Clemons, SI Stupp - Progress in Polymer Science, 2020 - Elsevier
One hundred years ago Hermann Staudinger was strongly criticized by his scientific peers
for his macromolecular hypothesis, but today it is hard to imagine a world without polymers …

Cyclic and linear tetrablock copolymers synthesized at speed and scale by Lewis Pair polymerization of a one-pot (meth) acrylic mixture and characterized at multiple …

RW Clarke, MR Caputo, L Polo Fonseca… - Journal of the …, 2024 - ACS Publications
Cyclic block copolymers (c BCP) are fundamentally intriguing materials, but their synthetic
challenges that demand precision in controlling both the monomer sequence and polymer …

Macrocyclic polymers: Synthesis, purification, properties and applications

J Ochs, CA Pagnacco, F Barroso-Bujans - Progress in Polymer Science, 2022 - Elsevier
Cyclic polymers present a topology that differ significantly from their linear counterparts due
to their circular structure and therefore, the lack of chain ends. These simple characteristics …