Sustainability assessment of mechanochemistry by using the twelve principles of green chemistry

KJ Ardila‐Fierro, JG Hernández - ChemSusChem, 2021 - Wiley Online Library
In recent years, mechanochemistry has been growing into a widely accepted alternative for
chemical synthesis. In addition to their efficiency and practicality, mechanochemical …

The many flavours of mechanochemistry and its plausible conceptual underpinnings

RT O'Neill, R Boulatov - Nature Reviews Chemistry, 2021 - nature.com
Mechanochemistry describes diverse phenomena in which mechanical load affects
chemical reactivity. The fuzziness of this definition means that it includes processes as …

Time‐resolved in situ monitoring of mechanochemical reactions

AAL Michalchuk, F Emmerling - … Chemie International Edition, 2022 - Wiley Online Library
Mechanochemical transformations offer environmentally benign synthesis routes, whilst
enhancing both the speed and selectivity of reactions. In this regard, mechanochemistry …

A guide to direct mechanocatalysis

S Hwang, S Grätz, L Borchardt - Chemical Communications, 2022 - pubs.rsc.org
Direct mechanocatalysis (DM) describes solvent-free catalytic reactions that are initiated by
mechanical forces in mechanochemical reactors such as ball mills. The distinctive feature of …

Tinkering with mechanochemical tools for scale up

JF Reynes, V Isoni, F García - … Chemie International Edition, 2023 - Wiley Online Library
Mechanochemistry provides an environmentally benign platform to develop more
sustainable chemical processes by limiting raw materials, energy use, and waste generation …

Toward Mechanistic Understanding of Mechanochemical Reactions Using Real-Time In Situ Monitoring

S Lukin, LS Germann, T Friščić… - Accounts of chemical …, 2022 - ACS Publications
Conspectus The past two decades have witnessed a rapid emergence of interest in
mechanochemistry–chemical and materials reactivity achieved or sustained by the action of …

Direct mechanocatalysis: using milling balls as catalysts

W Pickhardt, S Grätz, L Borchardt - Chemistry–A European …, 2020 - Wiley Online Library
Direct mechanocatalysis describes catalytic reactions under the involvement of mechanical
energy with the distinct feature of milling equipment itself being the catalyst. This novel type …

Raman spectroscopy for real-time and in situ monitoring of mechanochemical milling reactions

S Lukin, K Užarević, I Halasz - Nature Protocols, 2021 - nature.com
Solid-state milling has emerged as an alternative, sustainable approach for preparing
virtually all classes of compounds and materials. In situ reaction monitoring is essential to …

Direct amidation of esters by ball milling

WI Nicholson, F Barreteau, JA Leitch… - Angewandte …, 2021 - Wiley Online Library
The direct mechanochemical amidation of esters by ball milling is described. The
operationally simple procedure requires an ester, an amine, and substoichiometric KOtBu …

Leveraging mechanochemistry for sustainable polymer degradation

S Aydonat, AH Hergesell, CL Seitzinger, R Lennarz… - Polymer Journal, 2024 - nature.com
Over 8 billion tons of plastic have been produced to date, and a 100% reclamation recycling
strategy is not foreseeable. This review summarizes how the mechanochemistry of polymers …