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Sustainability assessment of mechanochemistry by using the twelve principles of green chemistry
In recent years, mechanochemistry has been growing into a widely accepted alternative for
chemical synthesis. In addition to their efficiency and practicality, mechanochemical …
chemical synthesis. In addition to their efficiency and practicality, mechanochemical …
The many flavours of mechanochemistry and its plausible conceptual underpinnings
Mechanochemistry describes diverse phenomena in which mechanical load affects
chemical reactivity. The fuzziness of this definition means that it includes processes as …
chemical reactivity. The fuzziness of this definition means that it includes processes as …
Time‐resolved in situ monitoring of mechanochemical reactions
Mechanochemical transformations offer environmentally benign synthesis routes, whilst
enhancing both the speed and selectivity of reactions. In this regard, mechanochemistry …
enhancing both the speed and selectivity of reactions. In this regard, mechanochemistry …
A guide to direct mechanocatalysis
Direct mechanocatalysis (DM) describes solvent-free catalytic reactions that are initiated by
mechanical forces in mechanochemical reactors such as ball mills. The distinctive feature of …
mechanical forces in mechanochemical reactors such as ball mills. The distinctive feature of …
Tinkering with mechanochemical tools for scale up
Mechanochemistry provides an environmentally benign platform to develop more
sustainable chemical processes by limiting raw materials, energy use, and waste generation …
sustainable chemical processes by limiting raw materials, energy use, and waste generation …
Toward Mechanistic Understanding of Mechanochemical Reactions Using Real-Time In Situ Monitoring
Conspectus The past two decades have witnessed a rapid emergence of interest in
mechanochemistry–chemical and materials reactivity achieved or sustained by the action of …
mechanochemistry–chemical and materials reactivity achieved or sustained by the action of …
Direct mechanocatalysis: using milling balls as catalysts
Direct mechanocatalysis describes catalytic reactions under the involvement of mechanical
energy with the distinct feature of milling equipment itself being the catalyst. This novel type …
energy with the distinct feature of milling equipment itself being the catalyst. This novel type …
Raman spectroscopy for real-time and in situ monitoring of mechanochemical milling reactions
Solid-state milling has emerged as an alternative, sustainable approach for preparing
virtually all classes of compounds and materials. In situ reaction monitoring is essential to …
virtually all classes of compounds and materials. In situ reaction monitoring is essential to …
Direct amidation of esters by ball milling
The direct mechanochemical amidation of esters by ball milling is described. The
operationally simple procedure requires an ester, an amine, and substoichiometric KOtBu …
operationally simple procedure requires an ester, an amine, and substoichiometric KOtBu …
Leveraging mechanochemistry for sustainable polymer degradation
Over 8 billion tons of plastic have been produced to date, and a 100% reclamation recycling
strategy is not foreseeable. This review summarizes how the mechanochemistry of polymers …
strategy is not foreseeable. This review summarizes how the mechanochemistry of polymers …