Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …

Five-membered aromatic rings containing Group 16 elements (O, S, Se, and Te), also
referred as chalcogenophenes, are ubiquitous building blocks for π-conjugated polymers …

The Suzuki–Miyaura and Buchwald–Hartwig coupling reactions are widely used to form
carbon-carbon (C–C) and carbon-nitrogen (C–N) bonds, respectively. We report the …

Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …

Renewable organic batteries represent a valuable option to store sustainably generated
energy and can play a major role in phasing out current carbon-based energy production …

Dinuclear PdI complexes have found widespread applications as diverse catalysts for a
multitude of transformations. Initially their ability to function as pre‐catalysts for low …

In this paper, we report on a one-step catalyst-transfer macrocyclization (CTM) reaction,
based on the Pd-catalyzed Buchwald–Hartwig cross-coupling reaction, selectively affording …

Catalyst-transfer polymerization has revolutionized the field of polymer synthesis due to its
living character, but for a given catalyst system, the polymer scope is rather narrow. Herein …

We describe a detailed investigation into why bulky ligands─ those that enable catalysis at
“12 e–” Pd0─ tend to promote overfunctionalization during Pd-catalyzed cross-couplings of …

The state-of-the-art bulk-heterojunction (BHJ)-type organic solar cells (OSCs) have achieved
over 19% power conversion efficiency (PCE), encouraging the development of the …