Switchable metallacycles and metallacages

HY Lin, YT Wang, X Shi, HB Yang, L Xu - Chemical Society Reviews, 2023 - pubs.rsc.org
Two-dimensional metallacycles and three-dimensional metallacages constructed by
coordination-driven self-assembly have attracted much attention because they exhibit …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

pH-Switching of the luminescent, redox, and magnetic properties in a spin crossover cobalt (ii) molecular nanomagnet

R Rabelo, L Toma, N Moliner, M Julve, F Lloret… - Chemical …, 2023 - pubs.rsc.org
The ability of mononuclear first-row transition metal complexes as dynamic molecular
systems to perform selective functions under the control of an external stimulus that …

CO 2-Responsive microemulsion: reversible switching from an apparent single phase to near-complete phase separation

Y Zhang, Y Zhang, C Wang, X Liu, Y Fang, Y Feng - Green Chemistry, 2016 - pubs.rsc.org
A CO2-switchable microemulsion was fabricated by introducing low-cost commercial N, N-
dimethyl-N-dodecyl amine into a sodium dodecyl sulphate–butanol–heptane solution. Upon …

Metallosupramolecular approach toward multifunctional magnetic devices for molecular spintronics

M Castellano, R Ruiz-Garcia, J Cano… - Coordination Chemistry …, 2015 - Elsevier
The work presented in this review constitutes a successful extension of our group's research
on the chemistry and physics of dinuclear copper (II) metallacyclophanes with aromatic …

Link between affinity and Cu (II) binding sites to amyloid-β peptides evaluated by a new water-soluble UV–visible ratiometric dye with a moderate Cu (II) affinity

A Conte-Daban, V Borghesani, S Sayen… - Analytical …, 2017 - ACS Publications
Being able to easily determine the Cu (II) affinity for biomolecules of moderate affinity is
important. Such biomolecules include amyloidogenic peptides, such as the well-known …

Slow magnetic relaxation in mononuclear gadolinium (III) and dysprosium (III) oxamato complexes

TT da Cunha, VMM Barbosa, WXC Oliveira… - Polyhedron, 2019 - Elsevier
A series of lanthanide (III) oxamate complexes of formula Na [Eu (4-HOpa) 4 (H 2 O)]∙ 2H 2 O
(1), Na [Gd (4-HOpa) 4 (H 2 O)]∙ 2H 2 O (2), Na [Dy (4-HOpa) 4 (H 2 O)]∙ 2H 2 O (3), and Na …

Mononuclear lanthanide (III)-oxamate complexes as new photoluminescent field-induced single-molecule magnets: solid-state photophysical and magnetic properties

RCA Vaz, IO Esteves, WXC Oliveira, J Honorato… - Dalton …, 2020 - pubs.rsc.org
Implementing additional optical (luminescent) properties into the well-known class of single-
molecule magnets (SMMs) is considered as a promising route toward obtaining the next …

Dicopper (II) pyrazolenophanes: Ligand effects on their structures and magnetic properties

I Castro, WP Barros, ML Calatayud, F Lloret… - Coordination Chemistry …, 2016 - Elsevier
The use of simple pyrazolate anions and related polychelating acyclic or macrocyclic
pyrazolate derivatives as bridging ligands, and occasionally additional blocking ligands, has …

When Molecular Magnetism Meets Supramolecular Chemistry: Multifunctional and Multiresponsive Dicopper (II) Metallacyclophanes as Proof-of-Concept for Single …

R Rabelo, SE Stiriba, D Cangussu, CLM Pereira… - Magnetochemistry, 2020 - mdpi.com
Molecular magnetism has made a long journey, from the fundamental studies on through-
ligand electron exchange magnetic interactions in dinuclear metal complexes with extended …