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Electrocatalysis as an enabling technology for organic synthesis
Electrochemistry has recently gained increased attention as a versatile strategy for
achieving challenging transformations at the forefront of synthetic organic chemistry …
achieving challenging transformations at the forefront of synthetic organic chemistry …
Radical C(sp3)–H functionalization and cross-coupling reactions
C–H functionalization reactions are playing an increasing role in the preparation and
modification of complex organic molecules, including pharmaceuticals, agrochemicals and …
modification of complex organic molecules, including pharmaceuticals, agrochemicals and …
Generalized biomolecular modeling and design with RoseTTAFold All-Atom
Deep-learning methods have revolutionized protein structure prediction and design but are
presently limited to protein-only systems. We describe RoseTTAFold All-Atom (RFAA), which …
presently limited to protein-only systems. We describe RoseTTAFold All-Atom (RFAA), which …
Nanozymes inspired by natural enzymes
Conspectus Nanozymes, nanomaterials with enzyme-like activities with high structural
stability, adjustable catalytic activity, functional diversity, recyclability, and feasibility in large …
stability, adjustable catalytic activity, functional diversity, recyclability, and feasibility in large …
Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
Copper-catalyzed radical relay in C (sp 3)–H functionalization
Z Zhang, P Chen, G Liu - Chemical Society Reviews, 2022 - pubs.rsc.org
Radical-involved transition metal (TM) catalysis has greatly enabled new reactivities in
recent decades. Copper-catalyzed radical relay offers enormous potential in C (sp3)–H …
recent decades. Copper-catalyzed radical relay offers enormous potential in C (sp3)–H …
Recent advances in electrocatalysis with phthalocyanines
S Yang, Y Yu, X Gao, Z Zhang, F Wang - Chemical Society Reviews, 2021 - pubs.rsc.org
Applications of phthalocyanines (Pcs) in electrocatalysis—including the oxygen reduction
reaction (ORR), the carbon dioxide reduction reaction (CO2RR), the oxygen evolution …
reaction (ORR), the carbon dioxide reduction reaction (CO2RR), the oxygen evolution …
An adjacent atomic platinum site enables single‐atom iron with high oxygen reduction reaction performance
The modulation effect has been widely investigated to tune the electronic state of single‐
atomic M‐N‐C catalysts to enhance the activity of oxygen reduction reaction (ORR) …
atomic M‐N‐C catalysts to enhance the activity of oxygen reduction reaction (ORR) …
Fe/Co dual metal catalysts modulated by S-ligands for efficient acidic oxygen reduction in PEMFC
Here, we report a conceptual strategy for introducing spatial sulfur (S)–bridge ligands to
regulate the coordination environment of Fe-Co-N dual-metal centers (Spa-S-Fe, Co/NC) …
regulate the coordination environment of Fe-Co-N dual-metal centers (Spa-S-Fe, Co/NC) …
Bioinspired porous three-coordinated single-atom Fe nanozyme with oxidase-like activity for tumor visual identification via glutathione
D Chen, Z **a, Z Guo, W Gou, J Zhao, X Zhou… - Nature …, 2023 - nature.com
Inspired by structures of natural metalloenzymes, a biomimetic synthetic strategy is
developed for scalable synthesis of porous Fe-N3 single atom nanozymes (pFeSAN) using …
developed for scalable synthesis of porous Fe-N3 single atom nanozymes (pFeSAN) using …