Electrocatalysis as an enabling technology for organic synthesis

LFT Novaes, J Liu, Y Shen, L Lu… - Chemical Society …, 2021 - pubs.rsc.org
Electrochemistry has recently gained increased attention as a versatile strategy for
achieving challenging transformations at the forefront of synthetic organic chemistry …

Radical C(sp3)–H functionalization and cross-coupling reactions

DL Golden, SE Suh, SS Stahl - Nature Reviews Chemistry, 2022 - nature.com
C–H functionalization reactions are playing an increasing role in the preparation and
modification of complex organic molecules, including pharmaceuticals, agrochemicals and …

Generalized biomolecular modeling and design with RoseTTAFold All-Atom

R Krishna, J Wang, W Ahern, P Sturmfels, P Venkatesh… - Science, 2024 - science.org
Deep-learning methods have revolutionized protein structure prediction and design but are
presently limited to protein-only systems. We describe RoseTTAFold All-Atom (RFAA), which …

Nanozymes inspired by natural enzymes

R Zhang, X Yan, K Fan - Accounts of Materials Research, 2021 - ACS Publications
Conspectus Nanozymes, nanomaterials with enzyme-like activities with high structural
stability, adjustable catalytic activity, functional diversity, recyclability, and feasibility in large …

Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis

PRD Murray, JH Cox, ND Chiappini, CB Roos… - Chemical …, 2021 - ACS Publications
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

Copper-catalyzed radical relay in C (sp 3)–H functionalization

Z Zhang, P Chen, G Liu - Chemical Society Reviews, 2022 - pubs.rsc.org
Radical-involved transition metal (TM) catalysis has greatly enabled new reactivities in
recent decades. Copper-catalyzed radical relay offers enormous potential in C (sp3)–H …

Recent advances in electrocatalysis with phthalocyanines

S Yang, Y Yu, X Gao, Z Zhang, F Wang - Chemical Society Reviews, 2021 - pubs.rsc.org
Applications of phthalocyanines (Pcs) in electrocatalysis—including the oxygen reduction
reaction (ORR), the carbon dioxide reduction reaction (CO2RR), the oxygen evolution …

An adjacent atomic platinum site enables single‐atom iron with high oxygen reduction reaction performance

A Han, X Wang, K Tang, Z Zhang, C Ye… - Angewandte Chemie …, 2021 - Wiley Online Library
The modulation effect has been widely investigated to tune the electronic state of single‐
atomic M‐N‐C catalysts to enhance the activity of oxygen reduction reaction (ORR) …

Fe/Co dual metal catalysts modulated by S-ligands for efficient acidic oxygen reduction in PEMFC

F Liu, L Shi, X Lin, B Zhang, Y Long, F Ye, R Yan… - Science …, 2023 - science.org
Here, we report a conceptual strategy for introducing spatial sulfur (S)–bridge ligands to
regulate the coordination environment of Fe-Co-N dual-metal centers (Spa-S-Fe, Co/NC) …

Bioinspired porous three-coordinated single-atom Fe nanozyme with oxidase-like activity for tumor visual identification via glutathione

D Chen, Z **a, Z Guo, W Gou, J Zhao, X Zhou… - Nature …, 2023 - nature.com
Inspired by structures of natural metalloenzymes, a biomimetic synthetic strategy is
developed for scalable synthesis of porous Fe-N3 single atom nanozymes (pFeSAN) using …