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Stimuli-responsive molecular brushes
Molecular brushes are composed of a flexible backbone and densely grafted side chains.
The conformation of molecular brushes is governed by side chains separated by a distance …
The conformation of molecular brushes is governed by side chains separated by a distance …
Physical biology of the cancer cell glycocalyx
The glycocalyx coating the outside of most cells is a polymer meshwork comprising proteins
and complex sugar chains called glycans. From a physical perspective, the glycocalyx has …
and complex sugar chains called glycans. From a physical perspective, the glycocalyx has …
Molecular structure of bottlebrush polymers in melts
Bottlebrushes are fascinating macromolecules that display an intriguing combination of
molecular and particulate features having vital implications in both living and synthetic …
molecular and particulate features having vital implications in both living and synthetic …
Materials design of highly branched bottlebrush polymers at the intersection of modeling, synthesis, processing, and characterization
Highly branched “bottlebrush” polymers are a class of macromolecules characterized by
side chains that are densely grafted from a backbone that is typically linear. Their unique …
side chains that are densely grafted from a backbone that is typically linear. Their unique …
Bottlebrush networks: a primer for advanced architectures
Bottlebrush networks (BBNs) are an exciting new class of materials with interesting physical
properties derived from their unique architecture. While great strides have been made in our …
properties derived from their unique architecture. While great strides have been made in our …
Combs and Bottlebrushes in a Melt
We use a combination of the coarse-grained molecular dynamics simulations and scaling
analysis to study conformations of bottlebrush and comb-like polymers in a melt. Our …
analysis to study conformations of bottlebrush and comb-like polymers in a melt. Our …
Synthesis of molecular brushes with block copolymer side chains using atom transfer radical polymerization
Brush macromolecules having poly (n-butyl acrylate-block-styrene) and poly (styrene-block-
n-butyl acrylate) side chains have been synthesized by the “grafting from” approach using …
n-butyl acrylate) side chains have been synthesized by the “grafting from” approach using …
Standard definitions of persistence length do not describe the local “intrinsic” stiffness of real polymer chains
HP Hsu, W Paul, K Binder - Macromolecules, 2010 - ACS Publications
On the basis of extensive Monte Carlo simulations of lattice models for linear chains under
good and Θ solvents conditions, and for bottle-brush polymers under good solvent …
good and Θ solvents conditions, and for bottle-brush polymers under good solvent …
Initiation efficiency in the synthesis of molecular brushes by grafting from via atom transfer radical polymerization
BS Sumerlin, D Neugebauer, K Matyjaszewski - Macromolecules, 2005 - ACS Publications
Grafting from via atom transfer radical polymerization (ATRP) was employed for the
synthesis of densely grafted molecular brushes. A poly (2-(2-bromopropionyl) oxyethyl …
synthesis of densely grafted molecular brushes. A poly (2-(2-bromopropionyl) oxyethyl …
Consequences of grafting density on the linear viscoelastic behavior of graft polymers
The linear viscoelastic behavior of poly (norbornene)-graft-poly (±-lactide) was investigated
as a function of grafting density and overall molar mass. Eight sets of polymers with grafting …
as a function of grafting density and overall molar mass. Eight sets of polymers with grafting …