Beyond click chemistry–supramolecular interactions of 1, 2, 3-triazoles

B Schulze, US Schubert - Chemical Society Reviews, 2014 - pubs.rsc.org
The research on 1, 2, 3-triazoles has been lively and ever-growing since its stimulation by
the advent of click chemistry. The attractiveness of 1H-1, 2, 3-triazoles and their derivatives …

Aromaticity as a cornerstone of heterocyclic chemistry

AT Balaban, DC Oniciu, AR Katritzky - Chemical reviews, 2004 - ACS Publications
This review is based on the following premises:(i) that heterocyclic chemistry is a key to the
understanding of life processes and to our efforts to improve the quality of life for humankind; …

Protodemetalation of (Bipyridyl) Ni (II)–Aryl Complexes Shows Evidence for Five-, Six-, and Seven-Membered Cyclic Pathways

PE Piszel, BJ Orzolek, AK Olszewski… - Journal of the …, 2023 - ACS Publications
Protonation of C–M bonds and its microscopic reverse, metalation of C–H bonds, are
fundamental steps in a variety of metal-catalyzed processes. As such, studies on protonation …

Tautomeric equilibria in relation to pi-electron delocalization

ED Raczyńska, W Kosińska, B Ośmiałowski… - Chemical …, 2005 - ACS Publications
Tautomerism, a particular case of isomerism, plays an important role in modern organic
chemistry, biochemistry, medicinal chemistry, pharmacology, molecular biology, and life …

The Mechanism of Rh (I)-Catalyzed Coupling of Benzotriazoles and Allenes Revisited: Substrate Inhibition, Proton Shuttling, and the Role of Cationic vs Neutral …

N Jannsen, F Reiß, HJ Drexler… - Journal of the …, 2024 - ACS Publications
Direct coupling of benzotriazole to unsaturated substrates such as allenes represents an
atom-efficient method for the construction of biologically and pharmaceutically interesting …

Visible-Light-Promoted α-C(sp3)–H Amination of Ethers with Azoles and Amides

Y Deng, Z Hu, J Xue, J Yin, T Zhu, S Liu - Organic Letters, 2024 - ACS Publications
A visible-light-induced highly efficient C (sp3)–H amination of ethers with amides and azoles
has been presented under mild conditions via a nitrogen-and carbon-centered radical …

Prototropic tautomerism of heterocycles: heteroaromatic tautomerism—general overview and methodology

J Elguero, AR Katritzky, OV Denisko - Advances in Heterocyclic Chemistry, 2000 - Elsevier
In 1963 one of us, together with JM Lagowski, published in Volumes 1 and 2 of Advances in
Heterocyclic Chemistry four chapters [63AHC (1), p. 312, p. 341; 63AHC (2), p. 3, p. 28] …

Cobalt-Catalyzed Intermolecular Markovnikov Hydroamination of Nonactivated Olefins: N2-Selective Alkylation of Benzotriazole

K Yahata, Y Kaneko, S Akai - Organic Letters, 2020 - ACS Publications
Cobalt-catalyzed Markovnikov-selective hydroamination of nonactivated olefins was
developed. Hydrogen atom transfer from a catalytically generated cobalt (III)–hydride …

Visible-Light-Promoted Site-Selective N1-Alkylation of Benzotriazoles with α-Diazoacetates

J Yang, J Duan, G Wang, H Zhou, B Ma, C Wu… - Organic …, 2020 - ACS Publications
A visible-light-promoted highly site-selective N 1-alkylation of benzotriazoles with diazo
compounds has been achieved under mild and metal-free conditions. Using cheap, readily …

Unlocking the N2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

K Xu, N Thieme, B Breit - Angewandte Chemie International …, 2014 - Wiley Online Library
The rhodium‐catalyzed, highly N2‐and N1‐selective coupling of benzotriazoles with allenes
is reported. The exceptionally high N2 and N1 selectivities were achieved by using a …