Catalytic Upcycling of Polyolefins

J Sun, J Dong, L Gao, YQ Zhao, H Moon… - Chemical …, 2024 - ACS Publications
The large production volumes of commodity polyolefins (specifically, polyethylene,
polypropylene, polystyrene, and poly (vinyl chloride)), in conjunction with their low unit …

[HTML][HTML] Retrieving back plastic wastes for conversion to value added petrochemicals: opportunities, challenges and outlooks

M Kumar, S Bolan, LP Padhye, M Konarova, SY Foong… - Applied Energy, 2023 - Elsevier
Plastic production and its unplanned management and disposal, has been shown to pollute
terrestrial, aquatic, and atmospheric environments. Petroleum-derived plastics do not …

Co-upcycling of polyvinyl chloride and polyesters

R Cao, MQ Zhang, Y Jiao, Y Li, B Sun, D **ao… - Nature …, 2023 - nature.com
Catalytic upcycling of plastic wastes to valuable chemicals offers the opportunity to
simultaneously address the enormous environmental problems associated with plastics and …

Role of bifunctional Ru/acid catalysts in the selective hydrocracking of polyethylene and polypropylene waste to liquid hydrocarbons

JE Rorrer, AM Ebrahim, Y Questell-Santiago… - ACS …, 2022 - ACS Publications
Hydrogenolysis of C–C bonds over Ru-based catalysts has emerged as a deconstruction
strategy to convert single-use polyolefin waste to liquid alkanes at relatively mild conditions …

RETRACTED: Hydrogenolysis of Polyethylene and Polypropylene into Propane over Cobalt-Based Catalysts

G Zichittella, AM Ebrahim, J Zhu, AE Brenner, G Drake… - JACS Au, 2022 - ACS Publications
The development of technologies to recycle polyethylene (PE) and polypropylene (PP),
globally the two most produced polymers, is critical to increase plastic circularity. Here, we …

Electronic modulation of metal-support interactions improves polypropylene hydrogenolysis over ruthenium catalysts

PA Kots, T **e, BC Vance, CM Quinn… - Nature …, 2022 - nature.com
Ruthenium (Ru) is the one of the most promising catalysts for polyolefin hydrogenolysis. Its
performance varies widely with the support, but the reasons remain unknown. Here, we …

Ni/SiO2 catalysts for polyolefin deconstruction via the divergent hydrogenolysis mechanism

BC Vance, PA Kots, C Wang, JE Granite… - Applied Catalysis B …, 2023 - Elsevier
Noble metal-based hydrogenolysis is emerging as a key chemical deconstruction
technology of polyolefins into valuable products. Still, the catalyst cost and availability are …

A general strategy and a consolidated mechanism for low-methane hydrogenolysis of polyethylene over ruthenium

C Wang, K Yu, B Sheludko, T **e, PA Kots… - Applied Catalysis B …, 2022 - Elsevier
Polyethylene (PE) is one of the most environment-threatening plastic waste. Its Ru-catalyzed
hydrogenolysis is rapid but produces too much methane. Here, low-density PE …

Catalytic hydroconversion processes for upcycling plastic waste to fuels and chemicals

J Wei, J Liu, W Zeng, Z Dong, J Song, S Liu… - Catalysis Science & …, 2023 - pubs.rsc.org
Plastic waste represents an environmental threat and a huge economic loss. Catalytic
hydroconversion of plastic wastes can enable valorization of plastic wastes to diverse value …

A two-stage strategy for upcycling chlorine-contaminated plastic waste

PA Kots, BC Vance, CM Quinn, C Wang… - Nature …, 2023 - nature.com
Chemical upcycling of polyolefin plastic waste to lubricant, wax and fuel-range
hydrocarbons over metal-based catalysts is a crucial technological solution to the enormous …