There and Back Again—The Journey of LiNiO2 as a Cathode Active Material

M Bianchini, M Roca‐Ayats, P Hartmann… - Angewandte Chemie …, 2019 - Wiley Online Library
This Review provides a comprehensive overview of LiNiO2 (LNO), almost 30 years after its
introduction as a cathode active material. We aim to highlight the physicochemical …

Narrowing the gap between theoretical and practical capacities in Li‐ion layered oxide cathode materials

MD Radin, S Hy, M Sina, C Fang, H Liu… - Advanced Energy …, 2017 - Wiley Online Library
Although layered lithium oxides have become the cathode of choice for state‐of‐the‐art Li‐
ion batteries, substantial gaps remain between the practical and theoretical energy …

Distinguishing bulk redox from near-surface degradation in lithium nickel oxide cathodes

L An, JEN Swallow, P Cong, R Zhang… - Energy & …, 2024 - pubs.rsc.org
Ni-rich layered oxide cathodes can deliver higher energy density batteries, but uncertainties
remain over their charge compensation mechanisms and the degradation processes that …

Tuning of Thermal Stability in Layered Li(NixMnyCoz)O2

J Zheng, T Liu, Z Hu, Y Wei, X Song… - Journal of the …, 2016 - ACS Publications
Understanding and further designing new layered Li (Ni x Mn y Co z) O2 (NMC)(x+ y+ z= 1)
materials with optimized thermal stability is important to rechargeable Li batteries (LIBs) for …

Jahn–Teller Distortions and Phase Transitions in LiNiO2: Insights from Ab Initio Molecular Dynamics and Variable-Temperature X-ray Diffraction

AR Genreith-Schriever, A Alexiu, GS Phillips… - Chemistry of …, 2024 - ACS Publications
The atomistic structure of lithium nickelate (LiNiO2), the parent compound of Ni-rich layered
oxide cathodes for Li-ion batteries, continues to elude a comprehensive understanding. The …

Long-Range and Local Structure in the Layered Oxide Li1.2Co0.4Mn0.4O2

J Bareno, M Balasubramanian, SH Kang… - Chemistry of …, 2011 - ACS Publications
The layered oxides being considered as intercalation compounds for lithium batteries
display significant differences between the long-range crystal structure and local …

Effects of cationic substitution on structural defects in layered cathode materials LiNiO 2

H Chen, JA Dawson, JH Harding - Journal of Materials Chemistry A, 2014 - pubs.rsc.org
The electrochemical properties of layered rock salt cathode materials are strongly influenced
by defects. The three most common defects in LiNiO2-based compounds, namely extra Ni, Li …

Surface properties of LiCoO2, LiNiO2 and LiNi1− xCoxO2

AW Moses, HGG Flores, JG Kim, MA Langell - Applied surface science, 2007 - Elsevier
The surface composition and chemical environment of LiCoO2, hexagonal LiNiO2, cubic
LiNiO2, and the mixed transition metal oxide LiNi0. 5Co0. 5O2 have been determined by …

First-principles simulation of the (Li–Ni–vacancy) O phase diagram and its relevance for the surface phases in Ni-Rich Li-Ion cathode materials

H Das, A Urban, W Huang, G Ceder - Chemistry of Materials, 2017 - ACS Publications
Despite several reports on the surface phase transformations from a layered to a disordered
spinel and a rock-salt structure at the surface of the Ni-rich cathodes, the precise structures …

A Fundamental Correlative Spectroscopic Study on Li1‐xNiO2 and NaNiO2

Q Jacquet, N Mozhzhukhina… - Advanced Energy …, 2024 - Wiley Online Library
The intricate relationship between local atomic arrangements and electronic states
significantly influences the electrochemical properties of Li‐ion battery cathode materials …