Sulfur donating extractants for the separation of trivalent actinides and lanthanides
The effective separation of trivalent actinides and lanthanides is capable of reducing the
long term radiation hazard associated with used nuclear fuel. This class of separation …
long term radiation hazard associated with used nuclear fuel. This class of separation …
Extension of the D3 and D4 London dispersion corrections to the full actinides series
Efficient dispersion corrections are an indispensable component of modern density
functional theory, semi-empirical quantum mechanical, and even force field methods. In this …
functional theory, semi-empirical quantum mechanical, and even force field methods. In this …
Isolation and characterization of a californium metallocene
Californium (Cf) is currently the heaviest element accessible above microgram quantities. Cf
isotopes impose severe experimental challenges due to their scarcity and radiological …
isotopes impose severe experimental challenges due to their scarcity and radiological …
Compression of curium pyrrolidine-dithiocarbamate enhances covalency
Curium is unique in the actinide series because its half-filled 5 f 7 shell has lower energy
than other 5 fn configurations, rendering it both redox-inactive and resistant to forming …
than other 5 fn configurations, rendering it both redox-inactive and resistant to forming …
Theoretical probing of size-selective crown ether macrocycle ligands for transplutonium element separation
Y Liu, CZ Wang, QY Wu, JH Lan, ZF Chai… - Inorganic …, 2022 - ACS Publications
Effective separation and recovery of chemically similar transplutonium elements from
adjacent actinides is extremely challenging in spent fuel reprocessing. Deep …
adjacent actinides is extremely challenging in spent fuel reprocessing. Deep …
Advancing the Am Extractant Design through the Interplay among Planarity, Preorganization, and Substitution Effects
Advancing the field of chemical separations is important for nearly every area of science and
technology. Some of the most challenging separations are associated with the americium …
technology. Some of the most challenging separations are associated with the americium …
N-Heterocyclic Carbene to Actinide d-Based π-bonding Correlates with Observed Metal–Carbene Bond Length Shortening Versus Lanthanide Congeners
Comparison of bonding and electronic structural features between trivalent lanthanide (Ln)
and actinide (An) complexes across homologous series' of molecules can provide insights …
and actinide (An) complexes across homologous series' of molecules can provide insights …
Advancing chelation chemistry for actinium and other+ 3 f-elements, Am, Cm, and La
A major chemical challenge facing implementation of 225Ac in targeted alpha therapy—an
emerging technology that has potential for treatment of disease—is identifying an 225Ac …
emerging technology that has potential for treatment of disease—is identifying an 225Ac …
Using redox-active ligands to generate actinide Ligand radical species
Using a redox-active dioxophenoxazine ligand, DOPO (DOPO= 2, 4, 6, 8-tetra-tert-butyl-1-
oxo-1 H-phenoxazine-9-olate), a family of actinide (U, Th, Np, and Pu) and Hf tris (ligand) …
oxo-1 H-phenoxazine-9-olate), a family of actinide (U, Th, Np, and Pu) and Hf tris (ligand) …
Expanding the Coordination of f-Block Metals with Tris [2-(2-methoxyethoxy) ethyl] amine: From Molecular Complexes to Cage-like Structures
Low-valent f-block metals have intrinsic luminescence, electrochemical, and magnetic
properties that are modulated with ligands, causing the coordination chemistry of these …
properties that are modulated with ligands, causing the coordination chemistry of these …