Materials design of highly branched bottlebrush polymers at the intersection of modeling, synthesis, processing, and characterization

T Pan, S Dutta, Y Kamble, BB Patel… - Chemistry of …, 2022 - ACS Publications
Highly branched “bottlebrush” polymers are a class of macromolecules characterized by
side chains that are densely grafted from a backbone that is typically linear. Their unique …

Some open challenges in polymer physics

GB McKenna, D Chen, SCH Mangalara… - Polymer Engineering …, 2022 - Wiley Online Library
Three subjects in polymer and soft matter physics are outlined in the present article. The first
relates to concepts of an ideal glass transition. We describe work on ultra‐stable glass …

The extreme of disentanglement: 100-fold viscosity reduction in model single-chain nanoparticles

Y Ruan, Q Zou, H Zhang, Y Zhang, H Zhang… - …, 2024 - ACS Publications
The melt rheology of single-chain nanoparticles (SCNPs), which are synthesized by
intrachain cross-linking of linear precursors, remains an unresolved issue. In this study, we …

Unexpected slow relaxation dynamics in pure ring polymers arise from intermolecular interactions

MQ Tu, O Davydovich, B Mei, PK Singh… - ACS Polymers …, 2023 - ACS Publications
Ring polymers have fascinated scientists for decades, but experimental progress has been
challenging due to the presence of linear chain contaminants that fundamentally alter …

Topological linking drives anomalous thickening of ring polymers in weak extensional flows

TC O'Connor, T Ge, M Rubinstein, GS Grest - Physical review letters, 2020 - APS
Molecular dynamics simulations confirm recent extensional flow experiments showing ring
polymer melts exhibit strong extension-rate thickening of the viscosity at Weissenberg …

Stress relaxation in symmetric ring-linear polymer blends at low ring fractions

D Parisi, J Ahn, T Chang, D Vlassopoulos… - …, 2020 - ACS Publications
We combine linear viscoelastic measurements and modeling in order to explore the
dynamics of blends of the same-molecular-weight ring and linear polymers in the regime of …

Nonlinear rheometry of entangled polymeric rings and ring-linear blends

D Parisi, M Kaliva, S Costanzo, Q Huang, PJ Lutz… - Journal of …, 2021 - pubs.aip.org
We present a comprehensive experimental rheological dataset for purified entangled ring
polystyrenes and their blends with linear chains in nonlinear shear and elongation. In …

Equilibrium structure and deformation response of 2D kinetoplast sheets

AR Klotz, BW Soh, PS Doyle - Proceedings of the National Academy of …, 2020 - pnas.org
The considerable interest in two-dimensional (2D) materials and complex molecular
topologies calls for a robust experimental system for single-molecule studies. In this work …

[HTML][HTML] Dynamics of poly [n] catenane melts

PM Rauscher, KS Schweizer, SJ Rowan… - The Journal of …, 2020 - pubs.aip.org
Inspired by advances in the chemical synthesis of interlocking polymer architectures,
extensive molecular dynamics simulations have been conducted to study the dynamical …

[HTML][HTML] Composite entanglement topology and extensional rheology of symmetric ring-linear polymer blends

TC O'Connor, T Ge, GS Grest - Journal of Rheology, 2022 - pubs.aip.org
Extensive molecular simulations are applied to characterize the equilibrium dynamics,
entanglement topology, and nonlinear extensional rheology of symmetric ring-linear …