Heterogenisation of polyoxometalates and other metal-based complexes in metal–organic frameworks: from synthesis to characterisation and applications in catalysis

P Mialane, C Mellot-Draznieks, P Gairola… - Chemical Society …, 2021 - pubs.rsc.org
The last few years have seen huge growing interest in the heterogenisation of molecular
catalysts since it allows combining the advantages of homogeneous and heterogeneous …

Structural analysis of molecular materials using the pair distribution function

MW Terban, SJL Billinge - Chemical Reviews, 2021 - ACS Publications
This is a review of atomic pair distribution function (PDF) analysis as applied to the study of
molecular materials. The PDF method is a powerful approach to study short-and …

Confining and Highly Dispersing Single Polyoxometalate Clusters in Covalent Organic Frameworks by Covalent Linkages for CO2 Photoreduction

M Lu, M Zhang, J Liu, TY Yu, JN Chang… - Journal of the …, 2022 - ACS Publications
Single clusters have attracted extensive research interest in the field of catalysis. However,
achieving a highly uniform dispersion of a single-cluster catalyst is challenging. In this work …

MOF encapsulating N‐heterocyclic carbene‐ligated copper single‐atom site catalyst towards efficient methane electrosynthesis

S Chen, WH Li, W Jiang, J Yang, J Zhu… - Angewandte …, 2022 - Wiley Online Library
The exploitation of highly efficient carbon dioxide reduction (CO2RR) electrocatalyst for
methane (CH4) electrosynthesis has attracted great attention for the intermittent renewable …

Metal-Free Catalysis: A Redox-Active Donor–Acceptor Conjugated Microporous Polymer for Selective Visible-Light-Driven CO2 Reduction to CH4

S Barman, A Singh, FA Rahimi… - Journal of the American …, 2021 - ACS Publications
Achieving more than a two-electron photochemical CO2 reduction process using a metal-
free system is quite exciting and challenging, as it needs proper channeling of electrons. In …

Confining charge-transfer complex in a metal-organic framework for photocatalytic CO2 reduction in water

S Karmakar, S Barman, FA Rahimi, D Rambabu… - Nature …, 2023 - nature.com
In the quest for renewable fuel production, the selective conversion of CO2 to CH4 under
visible light in water is a leading-edge challenge considering the involvement of kinetically …

Polyoxometalate@ metal–organic framework composites as effective photocatalysts

Y Liu, C Tang, M Cheng, M Chen, S Chen, L Lei… - ACS …, 2021 - ACS Publications
In the recent years, polyoxometalate (POM) encapsulated metal–organic framework (MOF)
composites have attracted much attention in photocatalysis. Both POMs and MOFs have …

Merging molecular catalysts and metal–organic frameworks for photocatalytic fuel production

PM Stanley, J Haimerl, NB Shustova, RA Fischer… - Nature Chemistry, 2022 - nature.com
In the effort to generate sustainable clean energy from abundant resources such as water
and carbon dioxide, solar fuel production—the combination of solar-light harvesting and the …

Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects

NF Suremann, BD McCarthy, W Gschwind… - Chemical …, 2023 - ACS Publications
The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …

Defects‐Induced Single‐Atom Anchoring on Metal–Organic Frameworks for High‐Efficiency Photocatalytic Nitrogen Reduction

G Ren, J Zhao, Z Zhao, Z Li, L Wang… - Angewandte Chemie …, 2024 - Wiley Online Library
Aiming to improve the photocatalytic activity in N2 fixation to produce ammonia, herein, we
proposed a photochemical strategy to fabricate defects, and further deposition of Ru single …