Heterogenisation of polyoxometalates and other metal-based complexes in metal–organic frameworks: from synthesis to characterisation and applications in catalysis
P Mialane, C Mellot-Draznieks, P Gairola… - Chemical Society …, 2021 - pubs.rsc.org
The last few years have seen huge growing interest in the heterogenisation of molecular
catalysts since it allows combining the advantages of homogeneous and heterogeneous …
catalysts since it allows combining the advantages of homogeneous and heterogeneous …
Structural analysis of molecular materials using the pair distribution function
This is a review of atomic pair distribution function (PDF) analysis as applied to the study of
molecular materials. The PDF method is a powerful approach to study short-and …
molecular materials. The PDF method is a powerful approach to study short-and …
Confining and Highly Dispersing Single Polyoxometalate Clusters in Covalent Organic Frameworks by Covalent Linkages for CO2 Photoreduction
M Lu, M Zhang, J Liu, TY Yu, JN Chang… - Journal of the …, 2022 - ACS Publications
Single clusters have attracted extensive research interest in the field of catalysis. However,
achieving a highly uniform dispersion of a single-cluster catalyst is challenging. In this work …
achieving a highly uniform dispersion of a single-cluster catalyst is challenging. In this work …
MOF encapsulating N‐heterocyclic carbene‐ligated copper single‐atom site catalyst towards efficient methane electrosynthesis
The exploitation of highly efficient carbon dioxide reduction (CO2RR) electrocatalyst for
methane (CH4) electrosynthesis has attracted great attention for the intermittent renewable …
methane (CH4) electrosynthesis has attracted great attention for the intermittent renewable …
Metal-Free Catalysis: A Redox-Active Donor–Acceptor Conjugated Microporous Polymer for Selective Visible-Light-Driven CO2 Reduction to CH4
Achieving more than a two-electron photochemical CO2 reduction process using a metal-
free system is quite exciting and challenging, as it needs proper channeling of electrons. In …
free system is quite exciting and challenging, as it needs proper channeling of electrons. In …
Confining charge-transfer complex in a metal-organic framework for photocatalytic CO2 reduction in water
In the quest for renewable fuel production, the selective conversion of CO2 to CH4 under
visible light in water is a leading-edge challenge considering the involvement of kinetically …
visible light in water is a leading-edge challenge considering the involvement of kinetically …
Polyoxometalate@ metal–organic framework composites as effective photocatalysts
Y Liu, C Tang, M Cheng, M Chen, S Chen, L Lei… - ACS …, 2021 - ACS Publications
In the recent years, polyoxometalate (POM) encapsulated metal–organic framework (MOF)
composites have attracted much attention in photocatalysis. Both POMs and MOFs have …
composites have attracted much attention in photocatalysis. Both POMs and MOFs have …
Merging molecular catalysts and metal–organic frameworks for photocatalytic fuel production
In the effort to generate sustainable clean energy from abundant resources such as water
and carbon dioxide, solar fuel production—the combination of solar-light harvesting and the …
and carbon dioxide, solar fuel production—the combination of solar-light harvesting and the …
Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects
The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …
Defects‐Induced Single‐Atom Anchoring on Metal–Organic Frameworks for High‐Efficiency Photocatalytic Nitrogen Reduction
G Ren, J Zhao, Z Zhao, Z Li, L Wang… - Angewandte Chemie …, 2024 - Wiley Online Library
Aiming to improve the photocatalytic activity in N2 fixation to produce ammonia, herein, we
proposed a photochemical strategy to fabricate defects, and further deposition of Ru single …
proposed a photochemical strategy to fabricate defects, and further deposition of Ru single …