Well-defined materials for heterogeneous catalysis: from nanoparticles to isolated single-atom sites

Z Li, S Ji, Y Liu, X Cao, S Tian, Y Chen, Z Niu… - Chemical …, 2019 - ACS Publications
The use of well-defined materials in heterogeneous catalysis will open up numerous new
opportunities for the development of advanced catalysts to address the global challenges in …

Nanostructured ceria-based materials: synthesis, properties, and applications

C Sun, H Li, L Chen - Energy & Environmental Science, 2012 - pubs.rsc.org
The controllable synthesis of nanostructured CeO2-based materials is an imperative issue
for environment-and energy-related applications. In this review, we present the recent …

Overturning CO2 Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal–Support Interactions

H **n, L Lin, R Li, D Li, T Song, R Mu… - Journal of the …, 2022 - ACS Publications
Encapsulation of metal nanoparticles by support-derived materials known as the classical
strong metal–support interaction (SMSI) often happens upon thermal treatment of supported …

Isotopic and in situ DRIFTS study of the CO2 methanation mechanism using Ni/CeO2 and Ni/Al2O3 catalysts

A Cárdenas-Arenas, A Quindimil… - Applied Catalysis B …, 2020 - Elsevier
The CO 2 methanation mechanism was studied for Ni/CeO 2 and Ni/Al 2 O 3 catalysts. The
higher methanation activity and selectivity of Ni/CeO 2 is attributed to: i) Ni/CeO 2 combines …

Tuning/exploiting strong metal-support interaction (SMSI) in heterogeneous catalysis

CJ Pan, MC Tsai, WN Su, J Rick, NG Akalework… - Journal of the Taiwan …, 2017 - Elsevier
Interactions between metals and supports are of fundamental interest in heterogeneous
catalysis. The electronic, geometric and bifunctional effects originating from Strong Metal …

Dry Reforming of Methane on a Highly‐Active Ni‐CeO2 Catalyst: Effects of Metal‐Support Interactions on C−H Bond Breaking

Z Liu, DC Grinter, PG Lustemberg… - Angewandte Chemie …, 2016 - Wiley Online Library
Ni‐CeO2 is a highly efficient, stable and non‐expensive catalyst for methane dry reforming
at relative low temperatures (700 K). The active phase of the catalyst consists of small …

Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles

GN Vayssilov, Y Lykhach, A Migani, T Staudt… - Nature materials, 2011 - nature.com
Interactions of metal particles with oxide supports can radically enhance the performance of
supported catalysts. At the microscopic level, the details of such metal–oxide interactions …

Strong metal–support interactions between gold nanoparticles and ZnO nanorods in CO oxidation

X Liu, MH Liu, YC Luo, CY Mou, SD Lin… - Journal of the …, 2012 - ACS Publications
The catalytic performances of supported gold nanoparticles depend critically on the nature
of support. Here, we report the first evidence of strong metal–support interactions (SMSI) …

Tailoring the catalytic properties of metal nanoparticles via support interactions

M Ahmadi, H Mistry… - The Journal of Physical …, 2016 - ACS Publications
The development of new catalysts for energy technology and environmental remediation
requires a thorough knowledge of how the physical and chemical properties of a catalyst …

Interfacial Frustrated Lewis Pairs of CeO2 Activate CO2 for Selective Tandem Transformation of Olefins and CO2 into Cyclic Carbonates

S Zhang, Z **a, Y Zou, F Cao, Y Liu… - Journal of the American …, 2019 - ACS Publications
Effective activation of CO2 is a prerequisite for efficient utilization of CO2 in organic
synthesis. Precisely controlling the interfacial events of solids shows potential for activation …