Charge transfer in metal–organic frameworks

R Haldar, A Ghosh, TK Maji - Chemical Communications, 2023‏ - pubs.rsc.org
Metal–organic frameworks (MOFs, also known as porous coordination polymers or PCPs)
are a novel class of crystalline porous material. The tailorable porous structure, in terms of …

Surface-coordinated metal-organic framework thin films (SURMOFs): From fabrication to energy applications

YH **ao, YB Tian, ZG Gu, J Zhang - EnergyChem, 2021‏ - Elsevier
The development of clean and sustainable energy is crucial to solve the increasingly serious
energy crisis. Metal-organic frameworks (MOFs) containing both inorganic and organic …

Exceptionally high charge mobility in phthalocyanine-based poly (benzimidazobenzophenanthroline)-ladder-type two-dimensional conjugated polymers

M Wang, S Fu, P Petkov, Y Fu, Z Zhang, Y Liu, J Ma… - Nature Materials, 2023‏ - nature.com
Two-dimensional conjugated polymers (2DCPs), composed of multiple strands of linear
conjugated polymers with extended in-plane π-conjugation, are emerging crystalline …

Inducing Circularly Polarized Luminescence by Confined Synthesis of Ultrasmall Chiral Carbon Nanodot Arrays in Pyrene-Based MOF Thin Film

YH **ao, ZZ Ma, XX Yang, DS Li, ZG Gu, J Zhang - ACS nano, 2023‏ - ACS Publications
Combining the features of the host–guest system and chirality is an efficient strategy to
achieve circularly polarized luminescence (CPL). Herein, well-defined chiral carbon …

Dimensionality mediated highly repeatable and fast transformation of coordination polymer single crystals for all-optical data processing

N Kulachenkov, M Barsukova, P Alekseevskiy… - Nano Letters, 2022‏ - ACS Publications
A family of coordination polymers (CPs) based on dynamic structural elements are of great
fundamental and commercial interest addressing modern problems in controlled molecular …

On–off conduction photoswitching in modelled spiropyran-based metal-organic frameworks

M Mostaghimi, H Pacheco Hernandez… - Communications …, 2023‏ - nature.com
Materials with photoswitchable electronic properties and conductance values that can be
reversibly changed over many orders of magnitude are highly desirable. Metal-organic …

Room-temperature quantum coherence of entangled multiexcitons in a metal-organic framework

A Yamauchi, K Tanaka, M Fuki, S Fujiwara… - Science …, 2024‏ - science.org
Singlet fission can generate an exchange-coupled quintet triplet pair state 5TT, which could
lead to the realization of quantum computing and quantum sensing using entangled multiple …

Nonadiabatic simulation of exciton dynamics in organic semiconductors using neural network-based frenkel hamiltonian and gradients

F Ghalami, PM Dohmen, M Krämer… - Journal of Chemical …, 2024‏ - ACS Publications
In this study, we present a multiscale method to simulate the propagation of Frenkel singlet
excitons in organic semiconductors (OSCs). The approach uses neural network models to …

Nanographene‐Based Metal‐Organic Framework Thin Films: Optimized Packing and Efficient Electron‐Hole Separation Yielding Efficient Photodetector

Z Xu, Y Liu, A Chandresh, PB Pati… - Advanced Functional …, 2024‏ - Wiley Online Library
Organic semiconductors, specifically polycyclic aromatic chromophores like pentacene,
coronene, and nanographenes (hexa‐peri‐hexabenzocoronene, HBC), are often utilized in …

GIWAXS characterization of metal–organic framework thin films and heterostructures: quantifying structure and orientation

JC Fischer, C Li, S Hamer, L Heinke… - Advanced Materials …, 2023‏ - Wiley Online Library
For optoelectronic applications of metal–organic framework (MOF) thin films, it is important to
be able to fabricate films and heterostructures that are highly oriented relative to the …