Graphene oxide synthesis, properties and characterization techniques: a comprehensive review

DG Trikkaliotis, AK Christoforidis, AC Mitropoulos… - ChemEngineering, 2021 - mdpi.com
The unique properties of graphene oxide (GO) have attracted the attention of the research
community and cost-effective routes for its production are studied. The type and percentage …

Trap** metallic oxide clusters inside fullerene cages

L Feng, Y Hao, A Liu, Z Slanina - Accounts of Chemical Research, 2019 - ACS Publications
Conspectus The sub-nanometer sized void inside a fullerene cage permits the
accommodation of a single atom, atomic cluster, or even small molecule, resulting in the …

U2@Ih(7)-C80: Crystallographic Characterization of a Long-Sought Dimetallic Actinide Endohedral Fullerene

X Zhang, Y Wang, R Morales-Martinez… - Journal of the …, 2018 - ACS Publications
The nature of actinide–actinide bonds has attracted considerable attention for a long time,
especially since recent theoretical studies suggest that triple and up to quintuple bonds …

Structurally Defined Water‐Soluble Metallofullerene Derivatives towards Biomedical Applications

Y Li, R Biswas, WP Kopcha, T Dubroca… - Angewandte …, 2023 - Wiley Online Library
Endohedral metallofullerenes (EMFs) are excellent carriers of rare‐earth element (REE)
ions in biomedical applications because they preclude the release of toxic metal ions …

Single Molecule Magnetism with Strong Magnetic Anisotropy and Enhanced Dy∙∙∙Dy Coupling in Three Isomers of Dy‐Oxide Clusterfullerene Dy2O@C82

W Yang, G Velkos, F Liu, SM Sudarkova… - Advanced …, 2019 - Wiley Online Library
A new class of single‐molecule magnets (SMMs) based on Dy‐oxide clusterfullerenes is
synthesized. Three isomers of Dy2O@ C82 with Cs (6), C3v (8), and C2v (9) cage …

Shape-adaptive single-molecule magnetism and hysteresis up to 14 K in oxide clusterfullerenes Dy 2 O@ C 72 and Dy 2 O@ C 74 with fused pentagon pairs and …

G Velkos, W Yang, YR Yao, SM Sudarkova, XY Liu… - Chemical …, 2020 - pubs.rsc.org
Dysprosium oxide clusterfullerenes Dy2O@ Cs (10528)–C72 and Dy2O@ C2 (13333)–C74
are synthesized and characterized by single-crystal X-ray diffraction. Carbon cages of both …

Alkali-metal coating: an effective method to inject electrons into cage molecules and achieve direct metal–metal bonds and spherical aromaticity for endohedral …

X Gu, P ** - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
Perfluorocubane (C8F8) has a hollow cage structure which can store an electron upon
electrochemical reduction. Similarly, fullerenes can encapsulate various metallic species …

Fluoride Clusterfullerenes: Tuning Metal–Metal Bonding and Magnetic Properties via Single Fluorine Atom Do**

Y Shen, Y Roselló, L Abella, J Qiu, X Du… - Journal of the …, 2024 - ACS Publications
Endohedral fullerenes are known for their exceptional ability to host metal clusters that
contain unique bonding motifs. In this study, we report a facile strategy to synthesize a new …

Overlooked Effects of La-4f Orbitals in Endohedral Metallofullerenes

B Li, X Gu, P ** - Inorganic Chemistry, 2022 - ACS Publications
For endohedral metallofullerenes (EMFs), a central issue is how to correctly describe the
intracluster and metal–cage interactions, which are critical for understanding their structures …

Tb2O@C2(13333)-C74: A Non-Isolated Pentagon Endohedral Fullerene Containing a Nearly Linear Tb–O–Tb Unit

JC Duchamp, HC Dorn, AL Wysocki, K Park… - Inorganic …, 2023 - ACS Publications
Terbium has been added to the list of elements that form oxide clusters inside fullerene
cages. Tb2O@ C 2 (13333)-C74 has been isolated as a byproduct of the electric arc …