The early years of 2, 2′-bipyridine—A ligand in its own lifetime

EC Constable, CE Housecroft - Molecules, 2019 - mdpi.com
The first fifty years of the chemistry of 2, 2′-bipyridine are reviewed from its first discovery in
1888 to the outbreak of the second global conflict in 1939. The coordination chemistry and …

Mononuclear organomolybdenum (VI) dioxo complexes: synthesis, reactivity, and catalytic applications

FE Kuehn, AM Santos, M Abrantes - Chemical reviews, 2006 - ACS Publications
Metal oxides are important in numerous catalytic industrial processes. The desire for models
of the metal oxide catalytic activity has contributed to the development of the research …

The borderless world of chemical bonding across the van der Waals crust and the valence region

J Echeverría, S Alvarez - Chemical Science, 2023 - pubs.rsc.org
The definition of the van der Waals crust as the spherical section between the atomic radius
and the van der Waals radius of an element is discussed and a survey of the application of …

Catalyst self-assembly accelerates bimetallic light-driven electrocatalytic H2 evolution in water

IN Cloward, T Liu, J Rose, T Jurado, AG Bonn… - Nature Chemistry, 2024 - nature.com
Hydrogen evolution is an important fuel-generating reaction that has been subject to
mechanistic debate about the roles of monometallic and bimetallic pathways. The molecular …

Can the formation of pharmaceutical cocrystals be computationally predicted? I. Comparison of lattice energies

N Issa, PG Karamertzanis, GWA Welch… - Crystal Growth and …, 2009 - ACS Publications
A cocrystal is only expected to form if it is thermodynamically more stable than the crystals of
its components. To test whether this can be predicted with a current computational …

Can the formation of pharmaceutical cocrystals be computationally predicted? 2. Crystal structure prediction

PG Karamertzanis, AV Kazantsev, N Issa… - Journal of Chemical …, 2009 - ACS Publications
We report a multistage lattice energy minimization methodology for generating stable
packing arrangements of cocrystals containing flexible molecules. In the first approximation …

Methyltrioxorhenium and its applications in olefin oxidation, metathesis and aldehyde olefination

FE Kühn, A Scherbaum, WA Herrmann - Journal of organometallic …, 2004 - Elsevier
Organorhenium (VII) oxides, most notably methyltrioxorhenium (MTO) and several of its
derivatives gained significant importance as extremely versatile catalysts for olefin oxidation …

Selective oxidation of styrene catalyzed by cerium-doped cobalt ferrite nanocrystals with greatly enhanced catalytic performance

J Tong, W Li, L Bo, H Wang, Y Hu, Z Zhang… - Journal of …, 2016 - Elsevier
The rare earth metal Ce-doped cobalt ferrite samples Ce x Co 1− x Fe 2 O 4 (x= 0.1, 0.3, 0.5)
were prepared by the sol–gel autocombustion route. The as-prepared samples were …

A Simple Entry to (η5-C5R5)chlorodioxomolybdenum(VI) Complexes (R = H, CH3, CH2Ph) and Their Use as Olefin Epoxidation Catalysts

M Abrantes, AM Santos, J Mink, FE Kühn… - …, 2003 - ACS Publications
The complexes (η5-C5R5) MoO2Cl (R= H, CH3 (Me), CH2Ph (Bz)) are readily prepared
from the parent carbonyls (η5-C5R5) Mo (CO) 3Cl upon reaction with t-BuOOH (TBHP) in n …

Immobilization of a molybdenum complex on bipyridine-based periodic mesoporous organosilica and its catalytic activity for epoxidation of olefins

S Ishikawa, Y Maegawa, M Waki, S Inagaki - ACS Catalysis, 2018 - ACS Publications
The dichlorodioxomolybdenum (VI) complex (MoO2Cl2) is an efficient and low-cost
homogeneous catalyst for a variety of organic reactions, but its activity usually decreases …