Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …
Degradable and recyclable polymers by reversible deactivation radical polymerization
Reversible deactivation radical polymerization (RDRP) provides unprecedented control over
polymer composition, size, functionality, and topology. Various materials, such as linear …
polymer composition, size, functionality, and topology. Various materials, such as linear …
Bulk depolymerization of poly (methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer
We present the bulk depolymerization of poly (methyl methacrylate)(PMMA) at significantly
lower temperatures than previously reported methods through the incorporation of …
lower temperatures than previously reported methods through the incorporation of …
Controlled-Radical Polymerization of α-Lipoic Acid: A General Route to Degradable Vinyl Copolymers
Here, we present the synthesis and characterization of statistical and block copolymers
containing α-lipoic acid (LA) using reversible addition–fragmentation chain-transfer (RAFT) …
containing α-lipoic acid (LA) using reversible addition–fragmentation chain-transfer (RAFT) …
Recyclable/degradable materials via the insertion of labile/cleavable bonds using a comonomer approach
C Lefay, Y Guillaneuf - Progress in Polymer Science, 2023 - Elsevier
Polymers have many advantages such as low weight, low cost, and, importantly, stability
under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …
under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …
100th anniversary of macromolecular science viewpoint: Degradable polymers from radical ring-opening polymerization: Latest advances, new directions, and …
Radical ring-opening polymerization (rROP) allows facile incorporation of labile groups (eg,
ester) into the main chain of vinyl polymers to obtain (bio) degradable materials. rROP has …
ester) into the main chain of vinyl polymers to obtain (bio) degradable materials. rROP has …
Aqueous ring‐opening polymerization‐induced self‐assembly (ROPISA) of N‐carboxyanhydrides
Reported here is the first aqueous ring‐opening polymerization (ROP) of N‐
carboxyanhydrides (NCAs) using α‐amino‐poly (ethylene oxide) as a macroinitiator to …
carboxyanhydrides (NCAs) using α‐amino‐poly (ethylene oxide) as a macroinitiator to …
Bulk Depolymerization of Methacrylate Polymers via Pendent Group Activation
In this study, we present an efficient approach for the depolymerization of poly (methyl
methacrylate)(PMMA) copolymers synthesized via conventional radical polymerization. By …
methacrylate)(PMMA) copolymers synthesized via conventional radical polymerization. By …
Industrial development of reversible-deactivation radical polymerization: is the induction period over?
M Destarac - Polymer Chemistry, 2018 - pubs.rsc.org
Reversible-deactivation radical polymerisation (RDRP) techniques are essential in modern
polymer chemistry. Over the years, they have become not only fantastic lab tools for the easy …
polymer chemistry. Over the years, they have become not only fantastic lab tools for the easy …
Radical approach to thioester-containing polymers
A new approach to radical ring-opening polymerization is presented that employs a new
thionolactone monomer to generate polymers with thioester-containing backbones. The use …
thionolactone monomer to generate polymers with thioester-containing backbones. The use …