A new strategy for enantioselective transition-metal catalysis is presented, wherein a H-bond
donor placed on the ligand of a cationic complex allows precise positioning of the chiral …

Gold catalysis has witnessed immense evolution in recent years, yet it still requires the use
of activators to render the common [AuCl (L)] complexes catalytically active. Herein, the H …

Gold (I) complexes of a chiral phosphoric acid-functionalized phosphine of the CPA-Phos
series enable the enantioselective multicomponent reactions between aldehydes …

Despite the unique position of gold catalysis in contemporary organic synthesis, this area of
research is notorious for requiring activators and/or additives that enable catalysis by …

Gold catalysis has emerged as an efficient tool in the field of synthetic organic chemistry.
Despite the significant progress, the need for high catalyst loadings has mainly hampered its …

The fabrication of various sensing devices and the ability to harmonize materials for a higher
degree of organization is essential for effective sensing systems. Materials with …

Gold catalysis has, over the past decades, provided innovative organic transformations
under mild conditions with high chemoselectivities. It receives steadily growing attention …

A library of gold (I) chloride complexes with phosphine ligands incorporating pendant (thio)
urea and squaramide H‐bond donors was prepared with the aim of promoting chloride …

A series of gold (I)–ethylene π-complexes containing a family of bulky phosphine ligands
has been prepared. The use of these sterically congested ligands is crucial to stabilize the …

We herein report the formation of fluorinated N-heterocyclic carbenes (NHCFs) that bear
fluorine atoms at the 4-and 5-positions of the imidazol-2-ylidene ring. Treatment of sodium …