Advanced functional liquid crystals

J Uchida, B Soberats, M Gupta, T Kato - Advanced Materials, 2022 - Wiley Online Library
Liquid crystals have been intensively studied as functional materials. Recently, integration of
various disciplines has led to new directions in the design of functional liquid‐crystalline …

Stimuli-responsive structure–property switchable polymer materials

ZM Png, CG Wang, JCC Yeo, JJC Lee… - … Systems Design & …, 2023 - pubs.rsc.org
The development of polymeric materials with switchable properties upon exposure to
external stimuli such as light, heat, force, acids/bases, and chemicals has attracted much …

Polymer mechanochromism from force-tuned excited-state intramolecular proton transfer

H Hu, X Cheng, Z Ma, RP Sijbesma… - Journal of the American …, 2022 - ACS Publications
Real-time monitoring of strain/stress in polymers is a big challenge to date. Herein, we for
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …

Fluorescent cyclophanes and their applications

I Roy, AHG David, PJ Das, JP David… - Chemical Society …, 2022 - pubs.rsc.org
With the serendipitous discovery of crown ethers by Pedersen more than half a century ago
and the subsequent introduction of host–guest chemistry and supramolecular chemistry by …

Ratiometric flap** force probe that works in polymer gels

T Yamakado, S Saito - Journal of the American Chemical Society, 2022 - ACS Publications
Polymer gels have recently attracted attention for their application in flexible devices, where
mechanically robust gels are required. While there are many strategies to produce tough …

Rotaxane-based dual function mechanophores exhibiting reversible and irreversible responses

T Muramatsu, Y Okado, H Traeger… - Journal of the …, 2021 - ACS Publications
Mechanochromic mechanophores permit the design of polymers that indicate mechanical
events through optical signals. Here we report rotaxane-based supramolecular …

Conformer Ring Flip Enhances Mechanochromic Performance of ansa-Donor–Acceptor–Donor Mechanochromic Torsional Springs

R Hertel, W Maftuhin, M Walter… - Journal of the American …, 2022 - ACS Publications
Mechanochromophores based on conformational changes of donor–acceptor–donor (DAD)
springs allow sensing of forces acting on polymer chains by monotonic changes of …

Folded perylene diimide loops as mechanoresponsive motifs

H Traeger, Y Sagara, DJ Kiebala, S Schrettl… - Angewandte …, 2021 - Wiley Online Library
A supramolecular mechanophore that can be integrated into polymers and indicates
deformation by a fluorescence color change is reported. Two perylene diimides (PDIs) were …

Excited State Charge‐Transfer Complexes Enable Fluorescence Color Changes in a Supramolecular Cyclophane Mechanophore

S Thazhathethil, T Muramatsu, N Tamaoki… - Angewandte …, 2022 - Wiley Online Library
Mechanochromic mechanophores are reporter molecules that indicate mechanical events
through changes of their photophysical properties. Supramolecular mechanophores in …

Cephalopod‐inspired design of photomechanically modulated display systems for on‐demand fluorescent patterning

H Shi, S Wu, M Si, S Wei, G Lin, H Liu, W **e… - Advanced …, 2022 - Wiley Online Library
Cephalopods can display variable body color/patterns upon environmental stimulation via
bioelectricity‐controlled muscle contraction/expansion of skin chromatophores. However, it …