Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision

VP Ananikov, LL Khemchyan, YV Ivanova… - Russian Chemical …, 2014 - iopscience.iop.org
The challenges of the modern society and the growing demand of high-technology sectors
of industrial production bring about a new phase in the development of organic synthesis. A …

Utilization of methylarenes as versatile building blocks in organic synthesis

R Vanjari, KN Singh - Chemical Society Reviews, 2015 - pubs.rsc.org
The development of practical and efficient methods for C–C and C–X bond formation has
attracted a great deal of current attention with the advent of C–H functionalization reactions …

Transition-metal-free direct C-3 alkylation of quinoxalin-2 (1 H)-ones with ethers

J Yuan, J Fu, J Yin, Z Dong, Y **ao, P Mao… - Organic Chemistry …, 2018 - pubs.rsc.org
A convenient and efficient transition-metal-free protocol for the synthesis of 3-alkyl
quinoxalin-2 (1H)-ones from the radical reaction of quinoxalin-2 (1H)-ones with ethers was …

Copper-catalyzed oxidative carbon–heteroatom bond formation: a recent update

X Zhu, S Chiba - Chemical Society Reviews, 2016 - pubs.rsc.org
Copper-catalyzed oxidative carbon–heteroatom bond formation: a recent update - Chemical
Society Reviews (RSC Publishing) DOI:10.1039/C5CS00882D Royal Society of Chemistry …

[HTML][HTML] Cross-dehydrogenative coupling for the intermolecular C–O bond formation

IB Krylov, VA Vil, AO Terent'ev - Beilstein journal of organic …, 2015 - beilstein-journals.org
The present review summarizes primary publications on the cross-dehydrogenative C–O
coupling, with special emphasis on the studies published after 2000. The starting …

Alkylative Dearomatization by Using an Unactivated Aryl Nitro Group as a Leaving Group: Access to Diversified Alkylated Spiro [5.5] trienones

D **a, XF Duan - Organic Letters, 2021 - ACS Publications
The cleavage of an unactivated aryl nitro group triggered by alkyl radicals enables a
dearomative cyclization, affording diversified alkylated spiro [5.5] trienones in good yields …

Copper-Catalyzed Esterification of Alkylbenzenes with Cyclic Ethers and Cycloalkanes via C(sp3)–H Activation Following Cross-Dehydrogenative Coupling

SK Rout, S Guin, W Ali, A Gogoi, BK Patel - Organic letters, 2014 - ACS Publications
A copper-catalyzed cross-dehydrogenative coupling strategy has been developed for the
synthesis of two classes of esters from simple solvents. The reaction of methylarenes with …

Easy access to benzylic esters directly from alkyl benzenes under metal-free conditions

G Majji, S Guin, A Gogoi, SK Rout… - Chemical …, 2013 - pubs.rsc.org
An efficient metal free protocol has been developed for the synthesis of benzylic esters via a
cross dehydrogenative coupling (CDC) involving alkylbenzene (s) as a self-or as a cross …

Trichloroisocyanuric acid: a versatile and efficient chlorinating and oxidizing reagent

S Gaspa, M Carraro, L Pisano… - European Journal of …, 2019 - Wiley Online Library
Trichloroisocyanuric acid (TCCA) is a versatile and efficient reagent for chlorination and
oxidation reactions. Depending on the reaction conditions employed, it can release either an …

Chemoselective Activation of sp3 vs sp2 C–H Bonds with Pd(II)

JM Curto, MC Kozlowski - Journal of the American Chemical …, 2015 - ACS Publications
The first selective coupling of a carbon nucleophile with methyl, ethyl, propyl, and butyl
arenes in the absence of a directing group is described. Pd (OAc) 2 double C–H activation …