Dynamic Covalent Chemistry for Synthesis and Co‐conformational Control of Mechanically Interlocked Molecules
Mechanically interlocked molecules have found extensive applications in areas all across
the physical sciences, from materials to catalysis and sensing. However, introducing …
the physical sciences, from materials to catalysis and sensing. However, introducing …
Sequence‐controlled synthesis of rotaxanes
Rotaxanes with well‐defined ring sequences are attractive synthetic goals in the
construction of functional materials associated with molecular shuttles and switches …
construction of functional materials associated with molecular shuttles and switches …
Self-sorting as a versatile strategy in the synthesis of rotaxanes and catenanes
Rotaxanes, pseudorotaxanes, and catenanes have attracted the interest of many
researchers because of the special features provided by the mechanical bond. The selective …
researchers because of the special features provided by the mechanical bond. The selective …
Sequence Engineering in Tuning the Circularly Polarized Luminescence of Aggregation-Induced Emission-Active Hetero [3] rotaxanes
Z Peng, PP Jia, XQ Wang, XL Zhao, HB Yang… - CCS …, 2024 - chinesechemsoc.org
Based on a [2] rotaxane precursor with exchangeable pentafluorophenyl ester stoppers, a
new wheel-assembling approach has been successfully developed for the precise …
new wheel-assembling approach has been successfully developed for the precise …
Balancing ring and stopper group size to control the stability of doubly threaded [3] rotaxanes
Synthesizing doubly threaded [3] rotaxanes requires the use of larger rings than more
traditional singly threaded [2] rotaxanes. A key challenge in accessing stable doubly …
traditional singly threaded [2] rotaxanes. A key challenge in accessing stable doubly …
Preprogrammed assembly of supramolecular polymer networks via the controlled disassembly of a metastable rotaxane
G Washino, MA Soto, S Wolff… - Communications …, 2022 - nature.com
In our daily life, some of the most valuable commodities are preprogrammed or
preassembled by a manufacturer; the end-user puts together the final product and gathers …
preassembled by a manufacturer; the end-user puts together the final product and gathers …
Concise and Efficient Synthesis of Sequentially Isomeric Hetero [3] rotaxanes
Stereoisomerism, stemming from the spatial orientation of components in molecular
structures, plays a decisive role in nature. While the unconventional bonding found in …
structures, plays a decisive role in nature. While the unconventional bonding found in …
Switchable protection and exposure of a sensitive squaraine dye within a redox active rotaxane
J Wasternack, HV Schröder, JF Witte… - Communications …, 2024 - nature.com
In nature, molecular environments in proteins can sterically protect and stabilize reactive
species such as organic radicals through non-covalent interactions. Here, we report a near …
species such as organic radicals through non-covalent interactions. Here, we report a near …
The Mobility of Homomeric Lasso‐and Daisy Chain‐Like Rotaxanes in Solution and in the Gas Phase as a Means to Study Structure and Switching Behaviour
A precise structural determination of supramolecular architectures is a non‐trivial challenge.
This daunting task can be made even more difficult when interlocked species are to be …
This daunting task can be made even more difficult when interlocked species are to be …
Encapsulation in Charged Droplets Generates Distorted Host‐Guest Complexes
The ability of various hydrogen‐bonded resorcinarene‐based capsules to bind α, ω‐
alkylbisDABCOnium (DnD) guests of different lengths was investigated in solution and in the …
alkylbisDABCOnium (DnD) guests of different lengths was investigated in solution and in the …