Magnetic relaxation in single-ion magnets formed by less-studied lanthanide ions Ce (III), Nd (III), Gd (III), Ho (III), Tm (II/III) and Yb (III)
Recent growth in the area of single-molecule magnets (SMMs) in general, and single-ion
magnets (SIMs) in particular, is due to the potential applications of this class of compounds …
magnets (SIMs) in particular, is due to the potential applications of this class of compounds …
Strong Ferromagnetic Exchange Coupling and Single-Molecule Magnetism in MoS43–-Bridged Dilanthanide Complexes
LE Darago, MD Boshart, BD Nguyen… - Journal of the …, 2021 - ACS Publications
We report the synthesis and characterization of the trinuclear 4d–4f compounds [Co
(C5Me5) 2][(C5Me5) 2Ln (μ-S) 2Mo (μ-S) 2Ln (C5Me5) 2], 1-Ln (Ln= Y, Gd, Tb, Dy) …
(C5Me5) 2][(C5Me5) 2Ln (μ-S) 2Mo (μ-S) 2Ln (C5Me5) 2], 1-Ln (Ln= Y, Gd, Tb, Dy) …
Slow magnetic relaxation in a europium (II) complex
Single-ion anisotropy is vital for the observation of Single-Molecule Magnet (SMM)
properties (ie, a slow dynamics of the magnetization) in lanthanide-based systems. In the …
properties (ie, a slow dynamics of the magnetization) in lanthanide-based systems. In the …
Molecular and Polymer Ln2M2 (Ln = Eu, Gd, Tb, Dy; M = Zn, Cd) Complexes with Pentafluorobenzoate Anions: The Role of Temperature and Stacking Effects in the …
MA Shmelev, MA Kiskin, JK Voronina, KA Babeshkin… - Materials, 2020 - mdpi.com
Varying the temperature of the reaction of [{Cd (pfb)(H2O) 4}+ n· n (pfb)−],[Ln2 (pfb) 6 (H2O)
8]· H2O (Hpfb= pentafluorobenzoic acid), and 1, 10-phenanthroline (phen) in MeCN …
8]· H2O (Hpfb= pentafluorobenzoic acid), and 1, 10-phenanthroline (phen) in MeCN …
Correlating the axial Zero Field Splitting with the slow magnetic relaxation in Gd III SIMs
Correlating the axial Zero Field Splitting with the slow magnetic relaxation in Gd III SIMs -
Chemical Communications (RSC Publishing) DOI:10.1039/D0CC07474H Royal Society of …
Chemical Communications (RSC Publishing) DOI:10.1039/D0CC07474H Royal Society of …
Giant exchange coupling and field-induced slow relaxation of magnetization in Gd 2@ C 79 N with a single-electron Gd–Gd bond
Magnetic properties of the azafullerene Gd2@ C79N are studied by SQUID magnetometry.
The effective exchange coupling constant jGd, e between the Gd spins and the spin of …
The effective exchange coupling constant jGd, e between the Gd spins and the spin of …
Slow magnetic relaxation in a palladium–gadolinium complex induced by electron density donation from the palladium ion
Incorporating palladium in the first coordination sphere of acetato‐bridged lanthanoid
complexes,[Pd2Ln2 (H2O) 2 (AcO) 10]⋅ 2 AcOH (Ln= Gd (1), Y (2), Gd0. 4Y1. 6 (3), Eu (4)) …
complexes,[Pd2Ln2 (H2O) 2 (AcO) 10]⋅ 2 AcOH (Ln= Gd (1), Y (2), Gd0. 4Y1. 6 (3), Eu (4)) …
Quasi-isotropic SMMs: slow relaxation of the magnetization in polynuclear Cu II/Mn II complexes
Three field induced SMMs built from quasi-isotropic cations like CuII and MnII have been
characterized, showing that relatively large clusters with quasi-negligible D and different …
characterized, showing that relatively large clusters with quasi-negligible D and different …
Magnetization dynamics and coherent spin manipulation of a propeller Gd (III) complex with the smallest helicene ligand
A homoleptic gadolinium (III) complex with the smallest helicene-type ligand, 1, 10-
phenanthroline-N, N′-dioxide (phendo)[Gd (phendo) 4](NO3) 3· x MeOH (phendo= 1, 10 …
phenanthroline-N, N′-dioxide (phendo)[Gd (phendo) 4](NO3) 3· x MeOH (phendo= 1, 10 …
Fe–Gd Ferromagnetic Cyclic Coordination Cluster [FeIII4GdIII4(teaH)8(N3)8(H2O)] with Magnetic Anisotropy─Theory and Experiment
D Schray, D Westerbeck, J Braun, Y Lan… - Inorganic …, 2023 - ACS Publications
The synthesis, structural, and magnetic characterization of [FeIII4LnIII4 (teaH) 8 (N3) 8
(H2O)](Ln= Gd and Y) and the previously reported isostructural Dy analogue are discussed …
(H2O)](Ln= Gd and Y) and the previously reported isostructural Dy analogue are discussed …