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Fundamentals and Catalytic Applications of CeO2-Based Materials
Cerium dioxide (CeO2, ceria) is becoming an ubiquitous constituent in catalytic systems for
a variety of applications. 2016 sees the 40th anniversary since ceria was first employed by …
a variety of applications. 2016 sees the 40th anniversary since ceria was first employed by …
Dynamic charge and oxidation state of Pt/CeO2 single-atom catalysts
The catalytic activity of metals supported on oxides depends on their charge and oxidation
state. Yet, the determination of the degree of charge transfer at the interface remains elusive …
state. Yet, the determination of the degree of charge transfer at the interface remains elusive …
Oxide-based nanomaterials for fuel cell catalysis: the interplay between supported single Pt atoms and particles
The concept of single atom catalysis offers maximum noble metal efficiency for the
development of low-cost catalytic materials. Among possible applications are catalytic …
development of low-cost catalytic materials. Among possible applications are catalytic …
Water-Mediated Mars–Van Krevelen Mechanism for CO Oxidation on Ceria-Supported Single-Atom Pt1 Catalyst
In water-promoted CO oxidation, water was thought not to directly participate in CO2
production. Here we report that via a water-mediated Mars–van Krevelen (MvK) mechanism …
production. Here we report that via a water-mediated Mars–van Krevelen (MvK) mechanism …
Dimethyl Carbonate Synthesis from CO2 over CeO2 with Electron‐Enriched Lattice Oxygen Species
G Hou, Q Wang, D Xu, H Fan, K Liu, Y Li… - Angewandte Chemie …, 2024 - Wiley Online Library
Direct synthesis of dimethyl carbonate (DMC) from CO2 plays an important role in carbon
neutrality, but its efficiency is still far from the practical application, due to the limited …
neutrality, but its efficiency is still far from the practical application, due to the limited …
Stabilizing platinum atoms on CeO2 oxygen vacancies by metal-support interaction induced interface distortion: mechanism and application
Z Jiang, M **g, X Feng, J **ong, C He… - Applied Catalysis B …, 2020 - Elsevier
Exploring thermally robust single atom catalysts (SACs) is of great significance. Here, we
develop a universal strategy for stabilizing Pt atoms on the mono-oxygen vacancies of CeO …
develop a universal strategy for stabilizing Pt atoms on the mono-oxygen vacancies of CeO …
Self-hydrating of a ceria-based catalyst enables efficient operation of solid oxide fuel cells on liquid fuels
The commercialization of solid oxide fuel cells (SOFCs) that run on liquid hydrocarbon fuels
is hindered by the poor coking tolerance of the state-of-the-art anode. Among the strategies …
is hindered by the poor coking tolerance of the state-of-the-art anode. Among the strategies …
Performance of DFT+U Approaches in the Study of Catalytic Materials
Catalytic materials are complex systems that contain different units, typically a carrier and an
active phase. For many reactions, redox-active materials constitute the active phase. Active …
active phase. For many reactions, redox-active materials constitute the active phase. Active …
Direct Conversion of Syngas into Light Olefins with Low CO2 Emission
S Wang, P Wang, D Shi, S He, L Zhang, W Yan… - ACS …, 2020 - ACS Publications
Direct conversion of syngas into light olefins over bifunctional catalysts has made significant
progress; the C2=–C4= selectivity in hydrocarbons reaches> 80%. Nevertheless, a relatively …
progress; the C2=–C4= selectivity in hydrocarbons reaches> 80%. Nevertheless, a relatively …
Shape-Controlled CeO2 Nanoparticles: Stability and Activity in the Catalyzed HCl Oxidation Reaction
C Li, Y Sun, I Djerdj, P Voepel, CC Sack, T Weller… - ACS …, 2017 - ACS Publications
CeO2 is a promising catalyst for the HCl oxidation (Deacon process) in order to recover Cl2.
Employing shape-controlled CeO2 nanoparticles (cubes, octahedrons, rods) with facets of …
Employing shape-controlled CeO2 nanoparticles (cubes, octahedrons, rods) with facets of …