Metallaphotoredox: the merger of photoredox and transition metal catalysis

AY Chan, IB Perry, NB Bissonnette, BF Buksh… - Chemical …, 2021 - ACS Publications
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Nitrogen-Centered Radicals in Functionalization of sp2 Systems: Generation, Reactivity, and Applications in Synthesis

C Pratley, S Fenner, JA Murphy - Chemical reviews, 2022 - ACS Publications
The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic
synthesis, and they continue to expand as our understanding of these reactive species …

Strategies to generate nitrogen-centered radicals that may rely on photoredox catalysis: development in reaction methodology and applications in organic synthesis

K Kwon, RT Simons, M Nandakumar… - Chemical …, 2021 - ACS Publications
For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …

Visible light-driven radical-mediated C–C bond cleavage/functionalization in organic synthesis

XY Yu, JR Chen, WJ **ao - Chemical Reviews, 2020 - ACS Publications
Thermal C–C bond cleavage reactions allow the construction of structurally diverse
molecular skeletons via predictable and efficient bond reorganizations. Visible light …

Carbon–Carbon Bond Cleavage for Late-Stage Functionalization

YF Liang, M Bilal, LY Tang, TZ Wang, YQ Guan… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) introduces functional group or structural modification at
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …

When light meets nitrogen-centered radicals: from reagents to catalysts

XY Yu, QQ Zhao, J Chen, WJ **ao… - Accounts of Chemical …, 2020 - ACS Publications
Conspectus Nitrogen-centered radicals (NCRs) are a versatile class of highly reactive
species that have a longer history than the classical carbon-based radicals in synthetic …

Metal–organic frameworks for food safety

PL Wang, LH **e, EA Joseph, JR Li, XO Su… - Chemical …, 2019 - ACS Publications
Food safety is a prevalent concern around the world. As such, detection, removal, and
control of risks and hazardous substances present from harvest to consumption will always …

Cleavage of carbon–carbon σ-bonds of four-membered rings

M Murakami, N Ishida - Chemical Reviews, 2020 - ACS Publications
This article reviews synthetic transformations involving cleavage of a carbon–carbon bond of
a four-membered ring, with a particular focus on the examples reported during the period …

pH-Stable Luminescent Metal–Organic Frameworks for the Selective Detection of Aqueous-Phase FeIII and CrVI Ions

SC Pal, D Mukherjee, MC Das - Inorganic Chemistry, 2022 - ACS Publications
The development of chemically stable metal–organic framework (MOF)-based luminescent
platforms for toxic ion detection in an aqueous medium is highly challenging because most …

Tailoring the properties of UiO-66 through defect engineering: a review

Y Feng, Q Chen, M Jiang, J Yao - Industrial & Engineering …, 2019 - ACS Publications
Defects, which are commonly in metal organic frameworks (MOFs), are closely related to the
performance of materials in various applications. Unlike other MOFs where metal ion …